[FeIII (OH)(tpena)]+(tpena–= N, N, N′-tris (2-pyridylmethyl) ethylenediamine-N′-acetate)
catalytically activates H2O2 with the concomitant formation of the active oxidants [FeIV …

A mild late-stage modification of pyrrolo [2, 1-a] isoquinolines was established through iron-
catalyzed oxidative dearomatization and peroxidation. Peroxylated pyrroloisoquinolines …

Precise delivery of a proton plays a key role in O2 activation at iron oxygenases, enabling
the crucial O− O cleavage step that generates the oxidizing high‐valent metal–oxo species …

Oxidation, which converts sulfides into sulfoxides, is a widely used method for producing
synthetic intermediates in various industries such as chemical, medicinal chemistry, and …

Formation of the O− O bond is considered the critical step in oxidative water cleavage to
produce dioxygen. High‐valent metal complexes with terminal oxo (oxido) ligands are …

The selective cleavage of C− N bonds in N‐containing compounds holds significant
research value in organic synthesis, particularly for the synthesis of promising polynitrogen …

Hydrogen peroxide is a versatile reductant that under the right conditions can react to form
dioxygen in an electrochemical reaction. This reaction has a low carbon footprint and …

Aqueous solutions of the iron (III) complex of N, N, N′-tris (2-pyridylmethyl)
ethylenediamine-N′-acetate (tpena) react with hypochlorite (ClO–) to produce the reactive …

The coupling of selective C–H activation with O2 activation is an important goal for organic
synthesis. New experimental and computational results, along with the results from …

In this work, a mild and sustainable catalytic aerobic epoxidation of alkenes catalyzed by
cobalt porphyrin was performed in the presence of sunflower seeds oil. Under ambient …