Coinage-metal-based cyclic trinuclear complexes with metal–metal interactions: theories to experiments and structures to functions

J Zheng, Z Lu, K Wu, GH Ning, D Li - Chemical Reviews, 2020 - ACS Publications
Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …

Highlights on the recent advances in gold chemistry—a photophysical perspective

VWW Yam, ECC Cheng - Chemical Society Reviews, 2008 - pubs.rsc.org
The presence of inter-and/or intra-molecular aurophilic interactions among the closed-shell
gold (I) centres in various systems has been studied from various aspects, including …

Highly selective and ultrasensitive detection of Hg2+ based on fluorescence quenching of Au nanoclusters by Hg2+–Au+ interactions

J Xie, Y Zheng, JY Ying - Chemical Communications, 2010 - pubs.rsc.org
A simple label-free method for the detection of Hg2+ ions with high selectivity and sensitivity
has been developed by using fluorescent Au NCs in aqueous media. The sensing …

Lysozyme-stabilized gold fluorescent cluster: Synthesis and application as Hg2+ sensor

H Wei, Z Wang, L Yang, S Tian, C Hou, Y Lu - Analyst, 2010 - pubs.rsc.org
Highly fluorescent gold clusters have been synthesized in basic aqueous solution by using
lysozyme as reducing and stabilizing agents. The lysozyme-stabilized gold fluorescent …

Rapid, selective, and ultrasensitive fluorimetric analysis of mercury and copper levels in blood using bimetallic gold–silver nanoclusters with “silver effect”-enhanced …

N Zhang, Y Si, Z Sun, L Chen, R Li, Y Qiao… - Analytical …, 2014 - ACS Publications
Bimetallic alloying gold–silver nanoclusters (Au-AgNCs) have been synthesized by a one-
pot biomineralization synthesis route at a vital molar ratio of Au/Ag precursors in the protein …

Metal effect on the supramolecular structure, photophysics, and acid− base character of trinuclear pyrazolato coinage metal complexes

MA Omary, MA Rawashdeh-Omary… - Inorganic …, 2005 - ACS Publications
Varying the coinage metal in cyclic trinuclear pyrazolate complexes is found to significantly
affect the solid-state packing, photophysics, and acid− base properties. The three isoleptic …

Bright phosphorescence of a trinuclear copper (I) complex: luminescence thermochromism, solvatochromism, and “concentration luminochromism”

HVR Dias, HVK Diyabalanage… - Journal of the …, 2003 - ACS Publications
A photophysical study is reported for the trinuclear copper (I) complex {[3, 5-(CF3) 2Pz] Cu}
3. The neutral compound exhibits multicolor bright phosphorescent emissions both in the …

Trinuclear metallacycles: Metallatriangles and much more

E Zangrando, M Casanova, E Alessio - Chemical Reviews, 2008 - ACS Publications
In 1990, Fujita and co-workers described the first example of a rationally designed
metallacycle, the molecular square [{Pd (en)(μ-4, 4′-bipy)} 4](NO3) 8, prepared by self …

Excited-State Interactions for [Au(CN)2-]n and [Ag(CN)2-]n Oligomers in Solution. Formation of Luminescent Gold−Gold Bonded Excimers and Exciplexes

MA Rawashdeh-Omary, MA Omary… - Journal of the …, 2001 - ACS Publications
Solutions of K [Au (CN) 2] and K [Ag (CN) 2] in water and methanol exhibit strong
photoluminescence. Aqueous solutions of K [Au (CN) 2] at ambient temperature exhibit …

Gold nanocluster-based fluorescent probes for near-infrared and turn-on sensing of glutathione in living cells

D Tian, Z Qian, Y Xia, C Zhu - Langmuir, 2012 - ACS Publications
In this study, a novel Au nanocluster (NC)-based fluorescent sensor has been designed for
near-infrared (NIR) and turn-on sensing of glutathione (GSH) in both living cells and human …