In this review, an attempt is made to systemise the rôle which bidentate phosphinamine (P,
N) ligands play in asymmetric catalysis. The ligands will be classified, not by the reaction to …

Stereoselective carbon-carbon bond formation via palladium-catalyzed asymmetric allylic
alkylation is a crucial strategy to access chiral natural products and active pharmaceutical …

In recent years, the coordination chemistry of chelated ligands contain-ing mixed
functionalities on transition metal centers has been an extremely active area of research. In …

Published data on the synthesis of rhodium and palladium complexes with optically active P,
N-bidentate ligands and their applications in homogeneous asymmetric catalysis are …

New Pd (0) olefin complexes, 2− 5, of a binaphthalene-based chiral P, N (oxazoline)
auxiliary,(S, R)-2-[4-(isopropyl) oxazol-2-yl]-2 '-diphenylphosphino-1, 1 '-binaphthyl, 1, have …

Air-stable palladium (0) precatalysts are advantageous for facilitating a variety of chemical
transformations and are desirable precursors for high-throughput experimentation studies …

The new chiral auxiliary (R)-2-ethylthio-1-(phenylethyl)-(R)-binaphthyl phosphite, 1, and
three stable Pd (0) olefin complexes containing this chelate, 2− 4, have been synthesized …

Novel, well-defined, coordinatively unsaturated NHC palladium (0) and nickel (0) complexes
have been synthesized and fully characterized. Mixed N-heterocyclic carbene− olefin …

A series of zerovalent palladium complexes Pd (NN)(alkene) of bi-or tridentate nitrogen
ligands of the general formula 6-R ''-C5H3N-(C (R ') NR)-2 (R ''= H, Me, CH NR '; R '= H, Me; …

Threefold symmetrical chiral podands may simplify the stereochemistry of key catalytic
intermediates for cases in which they only act as bidentate ligands. This applies to systems …