Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …

Conspectus Hypervalent iodine reagents find application as selective chemical oxidants in a
diverse array of oxidative transformations. The utility of these reagents is often ascribed to …

Conspectus Since the pioneering work by Thiele and Chichibabin, who synthesized the first
diradicals bridged by phenylene and biphenylene groups in 1904 and 1907, respectively …

Small molecule redox mediators convey interfacial electron transfer events into bulk solution
and can enable diverse substrate activation mechanisms in synthetic electrocatalysis. Here …

The present review highlights recent developments in the chemistry of sulfur radicals.
Background material essential to the understanding of these developments is briefly …

Herein, we present a detailed kinetic and thermodynamic analysis of the anodic allylic
esterification of alkenes as well as the bulk application of the anodic amination and …

The aerobic dehydrogenative lactonization of alkenoic acids facilitated by a cooperative
nonmetallic catalyst pair is reported. The title procedure relies on the adjusted interplay of a …

Synthesis of stable main‐group element‐based radicals represents one of the most
interesting topics in contemporary organometallic chemistry, because of their vital roles in …

Featuring an extra electron in the π* antibonding orbital, species with a 2‐center‐3‐electron
(2c3e) π bond without an underlying σ bond are scarcely known. Herein, we report the …