Controls on the isotopic composition of microbial methane

J Gropp, Q Jin, I Halevy - Science advances, 2022 - science.org
Microbial methane production (methanogenesis) is responsible for more than half of the
annual emissions of this major greenhouse gas to the atmosphere. Although the stable …

Kinetic and equilibrium reactions on natural and laboratory generation of thermogenic gases from Type II marine shale

X Li, J Horita - Geochimica et Cosmochimica Acta, 2022 - Elsevier
The phenomenon that laboratory pyrolysis experiments produce much wetter gases than
those in natural reservoirs is a long-recognized and debated problem in the investigation of …

Reversibility controls on extreme methane clumped isotope signatures from anaerobic oxidation of methane

J Liu, RL Harris, JL Ash, JG Ferry, SJE Krause… - … et Cosmochimica Acta, 2023 - Elsevier
Microbial anaerobic oxidation of methane (AOM) substantially mitigates atmospheric
methane emissions on Earth and is a process to consider for astrobiological targets where …

Position-specific carbon isotopes of propane in coal systems in China

Y Shuai, B Bai, X Liu, X Wang, J Guo, Y Xiong - Fuel, 2024 - Elsevier
Evaluating the origin and fate of hydrocarbons holds significance in many fields, such as
energy, geology, astrobiology, biosphere, and environment. However, challenges arise in …

Clumped methane isotopologue-based temperature estimates for sources of methane in marine gas hydrates and associated vent gases

E Lalk, T Pape, DS Gruen, N Kaul… - … et Cosmochimica Acta, 2022 - Elsevier
Gas hydrates stored in the continental margins of the world's oceans represent the largest
global reservoirs of methane. Determining the source and history of methane from gas …

Tracing the origin and formation mechanisms of coalbed gas from the Fuxin Basin in China using geochemical and isotopic signatures of the gas and coproduced …

X Chen, Y Wang, M Tao, Z Zhou, Z He… - International Journal of …, 2023 - Elsevier
Coalbed gas (CBG) is an unconventional natural gas with a large resource potential. In
order to determine its origins, formation pathways and mechanisms, studies on the …

Rate limits and isotopologue fractionations for microbial methanogenesis examined with combined pathway protein cost and isotopologue flow network models

S Ono, JH Rhim, EC Ryberg - Geochimica et Cosmochimica Acta, 2022 - Elsevier
Microbial methanogenesis produces a range of isotope (13 C/12 C and D/H) and
isotopologue (13 CH 3 D and 12 CH 2 D 2) fractionations. Differential reversibility of …

Moderate D/H ratios in methane ice on Eris and Makemake as evidence of hydrothermal or metamorphic processes in their interiors: Geochemical analysis

CR Glein, WM Grundy, JI Lunine, I Wong, S Protopapa… - Icarus, 2024 - Elsevier
Abstract Dwarf planets Eris and Makemake have surfaces bearing methane ice of unknown
origin. This ice can provide important insights into the origin and evolution of volatiles in the …

Experimental determination of hydrogen isotope exchange rates between methane and water under hydrothermal conditions

AC Turner, NJ Pester, M Bill, ME Conrad… - … et Cosmochimica Acta, 2022 - Elsevier
The hydrogen isotopic composition of methane (CH 4) is used as a fingerprint of gas origins.
Exchange of hydrogen isotopes between CH 4 and liquid water has been proposed to occur …

Clumped and conventional isotopes of natural gas reveal basin burial, denudation, and biodegradation history

JH Kim, AM Martini, S Ono, E Lalk, G Ferguson… - … et Cosmochimica Acta, 2023 - Elsevier
Formation and post-genetic alteration of hydrocarbons provide insights into the dynamic and
complex geologic, hydrologic, and microbial history of shallow crustal environments …