The asymmetric catalytic synthesis of 1, 2-diamines has received considerable interest,
especially in the last ten years, due to their presence in biologically active compounds and …

Abstract Halogen (fluorine, chlorine, bromine, iodine) or chalcogen (sulfur, selenium)‐
containing heterocycles are widely recognized as key building blocks in many natural …

Pd-catalyzed sequential hydroamination of readily available 1, 3-enynes is reported. The
redox-neutral process provides an efficient route to synthesize a broad scope of …

Electrophilic halogenation of alkenes is a powerful transformation offering a convenient
route for the construction of valuable functionalized molecules. However, as a highly …

Herein we report a catalyst-and metal-free visible-light-mediated protocol enabling the
iodoamination of miscellaneous olefins. This protocol is characterized by high yields under …

Cyclic carbamates are a common feature of small-molecule therapeutics, offering a
constrained hydrogen bond acceptor that is both polar and sterically small. Methods for their …

The mechanism of our previously reported catalytic asymmetric bromocyclization reactions
using 2, 2′-bis (diphenylphosphino)-1, 1′-binaphthyl (BINAP) monoxide was examined in …

Guided by the transition-metal hydrogen atom transfer and radical-polar crossover concepts,
we developed a functional-group-tolerant and scalable method for the synthesis of cyclic …

Despite the rapid growth of enantioselective halolactonization reactions in recent years,
most are effective only when forming smaller (6, 5, 4-membered) rings. Seven-membered ε …

Heterocyclic chemistry is an essential frontier in science and a source of novel biologically
active compounds. The development of innovative synthetic methodologies that allows …