Strategies to activate inert nitrogen molecules for efficient ammonia electrosynthesis: current status, challenges, and perspectives
The electrocatalytic N2 reduction reaction (NRR) offers an alternative to the traditional Haber–
Bosch (H–B) process for the synthesis of ammonia (NH3) and has received a surge of …
Bosch (H–B) process for the synthesis of ammonia (NH3) and has received a surge of …
Enzymatic carbon dioxide to formate: mechanisms, challenges and opportunities
H Chen, Y Huang, C Sha, JM Moradian… - … and Sustainable Energy …, 2023 - Elsevier
The reduction of carbon dioxide (CO 2) gas into soluble formate is one of the most promising
carbon neutralization strategies since it facilitates simultaneous fixation of carbon dioxide …
carbon neutralization strategies since it facilitates simultaneous fixation of carbon dioxide …
Progress of experimental and computational catalyst design for electrochemical nitrogen fixation
Large-scale ammonia synthesis via the electrochemical nitrogen reduction reaction (eNRR)
under mild reaction conditions represents a green prospect for agriculture, industry, and …
under mild reaction conditions represents a green prospect for agriculture, industry, and …
Nitrogen reduction by the Fe sites of synthetic [Mo3S4Fe] cubes
Y Ohki, K Munakata, Y Matsuoka, R Hara, M Kachi… - Nature, 2022 - nature.com
Nitrogen (N2) fixation by nature, which is a crucial process for the supply of bio-available
forms of nitrogen, is performed by nitrogenase. This enzyme uses a unique transition-metal …
forms of nitrogen, is performed by nitrogenase. This enzyme uses a unique transition-metal …
On the Nature of Three-Atom Metal Cluster Catalysis for N2 Reduction to Ammonia
C Cui, H Zhang, R Cheng, B Huang, Z Luo - ACS Catalysis, 2022 - ACS Publications
Catalytic N2 activation and reduction for ammonia synthesis has been subject of intense
research interest. Cluster-modified catalysts have been proposed as promising candidates …
research interest. Cluster-modified catalysts have been proposed as promising candidates …
Hydrophobicity tailoring of ferric covalent organic framework/MXene nanosheets for high‐efficiency nitrogen electroreduction to ammonia
H He, HM Wen, HK Li, P Li, J Wang, Y Yang… - Advanced …, 2023 - Wiley Online Library
Electrocatalytic nitrogen reduction reaction (NRR) represents a promising sustainable
approach for NH3 synthesis. However, the poor NRR performance of electrocatalysts is a …
approach for NH3 synthesis. However, the poor NRR performance of electrocatalysts is a …
Thiomolybdate clusters: from homogeneous catalysis to heterogenization and active sites
S Batool, M Langer, SN Myakala, M Heiland… - Advanced …, 2024 - Wiley Online Library
Thiomolybdates are molecular molybdenum‐sulfide clusters formed from Mo centers and
sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due …
sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due …
Synthetic access to a framework-stabilized and fully sulfided analogue of an Anderson polyoxometalate that is catalytically competent for reduction reactions
Polyoxometalates (POMs) featuring 7, 12, 18, or more redox-accessible transition metal ions
are ubiquitous as selective catalysts, especially for oxidation reactions. The corresponding …
are ubiquitous as selective catalysts, especially for oxidation reactions. The corresponding …
An Iron–Sulfur Cluster with a Highly Pyramidalized Three-Coordinate Iron Center and a Negligible Affinity for Dinitrogen
Attempts to generate open coordination sites for N2 binding at synthetic Fe–S clusters often
instead result in cluster oligomerization. Recently, it was shown for Mo–Fe–S clusters that …
instead result in cluster oligomerization. Recently, it was shown for Mo–Fe–S clusters that …
Evidence for low-valent electronic configurations in iron–sulfur clusters
AC Brown, NB Thompson… - Journal of the American …, 2022 - ACS Publications
Although biological iron–sulfur (Fe–S) clusters perform some of the most difficult redox
reactions in nature, they are thought to be composed exclusively of Fe2+ and Fe3+ ions, as …
reactions in nature, they are thought to be composed exclusively of Fe2+ and Fe3+ ions, as …