3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Polymer-supported Schiff base complexes in oxidation reactions

KC Gupta, AK Sutar, CC Lin - Coordination Chemistry Reviews, 2009 - Elsevier
Polymer-supported Schiff base complexes of metal ions show high catalytic activity in
comparison to their unsupported analogues. The catalytic activity of metal complexes of …

Catalytic non‐enzymatic kinetic resolution

H Pellissier - Advanced Synthesis & Catalysis, 2011 - Wiley Online Library
While tremendous advances have been made in asymmetric synthesis, the resolution of
racemates is still the most important industrial approach to the synthesis of chiral …

Organocatalytic oxidation. Asymmetric epoxidation of olefins catalyzed by chiral ketones and iminium salts

OA Wong, Y Shi - Chemical reviews, 2008 - ACS Publications
Dioxiranes can be generated in situ10, 13 from ketones and Oxone (2KHSO5· KHSO4·
K2SO4)(Scheme 1). 14 In principle, only a catalytic amount of ketone should be needed …

Oxovanadium complexes in catalytic oxidations

JAL Da Silva, JJRF da Silva, AJL Pombeiro - Coordination Chemistry …, 2011 - Elsevier
This contribution is an overview on recent advances (since 2000) on the application of
oxovanadium complexes as catalysts or mediators for oxidations by molecular oxygen …

Catalytic kinetic resolution of cyclic secondary amines

M Binanzer, SY Hsieh, JW Bode - Journal of the American …, 2011 - ACS Publications
The catalytic resolution of racemic cyclic amines has been achieved by an enantioselective
amidation reaction featuring an achiral N-heterocyclic carbene catalyst and a new chiral …

Convenient and mild epoxidation of alkenes using heterogeneous cobalt oxide catalysts

D Banerjee, RV Jagadeesh, K Junge… - Angewandte …, 2014 - Wiley Online Library
A general epoxidation of aromatic and aliphatic olefins has been developed under mild
conditions using heterogeneous CoxOy–N/C (x= 1, 3; y= 1, 4) catalysts and tert‐butyl …

Metal-catalyzed asymmetric sulfoxidation, epoxidation and hydroxylation by hydrogen peroxide

H Srour, P Le Maux, S Chevance… - Coordination Chemistry …, 2013 - Elsevier
The development of environmentally benign reactions is an important goal in synthetic
organic chemistry and chemical engineering. However, catalytic enantioselective oxidations …

Substrate directed asymmetric reactions

S Bhadra, H Yamamoto - Chemical reviews, 2018 - ACS Publications
Historically, reagent controlled reactions (mechanism controlled reactions) have played a
significant role in the asymmetric synthesis of complex structures. In contrast, today's …

Recent advances in vanadium catalyzed oxygen transfer reactions

G Licini, V Conte, A Coletti, M Mba, C Zonta - Coordination Chemistry …, 2011 - Elsevier
Vanadium complexes have proven to be effective catalysts for the activation of peroxides
and the selective oxidation of substrates like bromides, sulfides and alkenes. Besides their …