The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Synthesis strategies to control the Al distribution in zeolites: thermodynamic and kinetic aspects

J Bae, M Dusselier - Chemical Communications, 2023 - pubs.rsc.org
The activity and selectivity of acid-catalyzed chemistry is highly dependent on the Brønsted
and Lewis acid sites generated by Al substitutions in a zeolite framework with the desired …

Controlling nucleation pathways in zeolite crystallization: seeding conceptual methodologies for advanced materials design

R Jain, AJ Mallette, JD Rimer - Journal of the American Chemical …, 2021 - ACS Publications
A core objective of synthesizing zeolites for widespread applications is to produce materials
with properties and corresponding performances that exceed conventional counterparts …

Hierarchical catalysts prepared by interzeolite transformation

MJ Mendoza-Castro, E De Oliveira-Jardim… - Journal of the …, 2022 - ACS Publications
Interzeolite transformation has been used to produce a novel family of hierarchical catalysts
featuring excellent textural properties, strong acidity, and superior catalytic performance for …

On the key role of aluminium and other heteroatoms during interzeolite conversion synthesis

J Devos, MA Shah, M Dusselier - RSC advances, 2021 - pubs.rsc.org
Interzeolite conversion, a synthesis technique for several zeolite frameworks, has recently
yielded a large amount of high-performing catalytic zeolites. Yet, the mechanisms behind the …

Strategies to control reversible and irreversible deactivation of ZSM-5 zeolite during the conversion of methanol to propylene (MTP): A review

A Zabihpour, J Ahmadpour, F Yaripour - Chemical Engineering Science, 2023 - Elsevier
Despite the favorable properties, ZSM-5 still suffers from deposition of coke in vital pores of
catalyst (reversible deactivation) as well as dealumination (irreversible deactivation) due to …

Seed-Assisted zeolite synthesis: The impact of seeding conditions and interzeolite transformations on crystal structure and morphology

R Jain, JD Rimer - Microporous and Mesoporous Materials, 2020 - Elsevier
Seed-assisted approaches in zeolite synthesis differ from classical processes in that the
seeds tend to dissolve, giving rise to an unknown memory of the parent crystal structure that …

Linking synthesis and structure descriptors from a large collection of synthetic records of zeolite materials

K Muraoka, Y Sada, D Miyazaki, W Chaikittisilp… - Nature …, 2019 - nature.com
Correlating synthesis conditions and their consequences is a significant challenge,
particularly for materials formed as metastable phases via kinetically controlled pathways …

Tracking the rearrangement of atomic configurations during the conversion of FAU zeolite to CHA zeolite

K Muraoka, Y Sada, A Shimojima, W Chaikittisilp… - Chemical …, 2019 - pubs.rsc.org
In order to realize designed synthesis, understanding the formation mechanism of zeolites at
an atomic level has long been aspired, but remains challenging due to the fact that the …

Recent advances in zeolite-encapsulated metal catalysts: A suitable catalyst design for catalytic biomass conversion

M Limlamthong, ACK Yip - Bioresource Technology, 2020 - Elsevier
Metal clusters and nanoparticles, which have been used to tune the acidity of zeolite
support, are beneficial for promoting the catalytic performance of various reaction processes …