The review surveys the pathways of formation of crystalline oligomeric oxoalkoxides M mO n
(OR) p, which are products of partially controlled (or uncontrolled) hydrolysis, oxidation …

Double metal alkoxides of lithium, also called heterometallic or bimetallic alkoxides, are a
large group within the double metal alkoxide realm. Many of the synthetic procedures known …

Intermetallic lithium− magnesium hexamethyldisilazide [{(Me3Si) 2N} 3LiMg], 1, has been
synthesized from a nonstoichiometric 2: 1 ratio of LHMDS and Mg (HMDS) 2 in …

Four Fe (III) compounds and one Fe (II) compound containing mononuclear, homoleptic,
fluorinated phenolate anions of the form [Fe (OAr) m] n− have been prepared in which ArF …

RMgBr (R Ph, iPr) and MgY2 (Y= iPr, C⋮ CPh, NMe2, NEt2, NPh2) react with carbon
dioxide, yielding different bridging carboxylato and carbamato magnesium …

This paper presents the synthesis and characterization of new homoleptic lithium
magnesiate reagents incorporating the silyl-substituted alkyl ligand CH2SiMe3 in the …

A series of carbodiimide insertion products were prepared using various aluminum reagents
(viz., AlR3 (R= Me, Et), AlX2Y (X= Cl, R; Y= Cl, NR '2)) and 1, 3-diisopropyl-and 1, 3-di-tert …

Two series of homoleptic phenolate complexes with fluorinated aryloxide ligands A2 [M
(OAr) 4] with M= Co2+ or Cu2+, OAr-=(OC6F5)-(OArF) or {3, 5-OC6H3 (CF3) 2}-(OAr '), A+ …

As part of ongoing investigations of battery electrolytes and additives based on derivatives of
1, 1, 1, 3, 3, 3-hexafluoroisopropanol, the solvent-free hexameric precursor [Li (μ 3-OCH (CF …

Three new mixed lithium− heavier alkali metal tert-butoxides [(t-BuO) 8Li4M4](M= Na, Rb,
Cs) are reported which, added to the previously discovered potassium analogue [(t-BuO) …