Glycal-derived δ-hydroxy α, β-unsaturated aldehydes (Perlin aldehydes): versatile building blocks in organic synthesis

LVR Reddy, V Kumar, R Sagar, AK Shaw - Chemical Reviews, 2013 - ACS Publications
The presence of hydroxyl functionalities and well-defined chiral centers in carbohydrates as
well as their natural abundance have attracted chemists worldwide to exploit this class of …

Recent applications of the Wittig reaction in alkaloid synthesis

MM Heravi, V Zadsirjan, H Hamidi, M Daraie… - The Alkaloids: Chemistry …, 2020 - Elsevier
The Wittig reaction is the chemical reaction of an aldehyde or ketone with a triphenyl
phosphonium ylide (the Wittig reagent) to afford an alkene and triphenylphosphine oxide …

Metal free synthesis of 2, 3-dideoxy-α, β-unsaturated carbohydrate enals (Perlin aldehydes)

K Singh, SS Behera, R Tyagi, G Tiwari, R Sagar - Carbohydrate Research, 2023 - Elsevier
A metal free synthesis of enantiopure 2, 3-dideoxy-α, β-unsaturated carbohydrate enals
(Perlin aldehydes), in CH 3 CN-0.02 NH 2 SO 4 in water (1: 1, v/v) with 0.5 equivalent …

One-pot construction of carbohydrate scaffolds mediated by metal catalysts

MM Mukherjee, SK Maity, R Ghosh - RSC advances, 2020 - pubs.rsc.org
Owing to the environmental concern worldwide and also due to cost, time and labour issues,
use of one-pot reactions [domino/cascade/tandem/multi-component (MC) or sequential] has …

Domino Imino-Aldol− Aza-Michael Reaction: One-Pot Diastereo-and Enantioselective Synthesis of Piperidines

MK Ghorai, S Halder, RK Das - The Journal of Organic Chemistry, 2010 - ACS Publications
Addition of α-arylmethylidene-or α-alkylidene-β-keto ester enolate to N-activated aldimines
via the imino aldol pathway followed by intramolecular aza-Michael reaction in a domino …

A concise enantioselective synthesis of (2S, 3S)-3-hydroxypipecolic acid via proline catalyzed α-aminooxylation of aldehydes and Pd-catalyzed ether directed aza …

BB Ahuja, A Sudalai - Tetrahedron: Asymmetry, 2015 - Elsevier
An efficient approach to (2S, 3S)-3-hydroxypipecolic acid with an overall yield of 10.2% and
98% ee starting from 1, 5-pentanediol has been developed. The key steps employed in the …

InBr3-Catalyzed Glycosidation of Glycals with Arylamines: An Alternative Approach To Access 4-Aminocyclopent-2-enones

F Li, C Ding, M Wang, Q Yao… - The Journal of Organic …, 2011 - ACS Publications
To turn side products into major products, a novel strategy to access biologically active 4-
aminocyclopent-2-enones was developed. These compounds were originally identified as …

Stereoselective Syntheses of (+)-2-epi-Deoxoprosopinine, (−)-Deoxoprosophylline, (+)-cis-195A, and 2,5-Di-epi-cis-195A from a Common Chiral Nonracemic …

K Annadi, AGH Wee - The Journal of Organic Chemistry, 2015 - ACS Publications
Approaches toward the syntheses of alkaloids belonging to the 2, 6-disubstituted 3-
hydroxypiperidine and cis-decahydroquinoline (cis-DHQ) classes of alkaloids are …

Total Synthesis of GE81112A: An Orthoester-Based Approach

S Fayad, A Jafari, SMM Schuler, M Kurz… - The Journal of …, 2023 - ACS Publications
The GE81112 series, consisting of three naturally occurring tetrapeptides and synthetic
derivatives, is evaluated as a potential lead structure for the development of a new …

A concise total synthesis of (+)-deoxocassine and (−)-deoxoprosophylline from d-xylose

C Kishore, AS Reddy, JS Yadav, BVS Reddy - Tetrahedron Letters, 2012 - Elsevier
A concise total synthesis of (+)-deoxocassine (1) and (−)-deoxoprosophylline (2) has been
achieved for the first time from d-xylose. The key steps involved in these synthesis are alkyl …