Chlorophylls make Earth green, are the central constituents in the engine of photosynthesis,
and not surprisingly have garnered immense attention. A chlorin, the core chromophore of a …

The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

Abstract Ethyl 2‐acrylamido‐4, 5, 6, 7‐tetrahydrobenzo [b] thiophene‐3‐carboxylate as well
as its corresponding bis‐derivatives, 5–10, with aliphatic linkers were synthesized, fully …

Conspectus Naturally occurring porphyrins and hydroporphyrins vary with respect to their
ring substituents and oxidation states, but their tetrapyrrolic frameworks remain fully …

In recent years, several synthetic strategies aiming at the peripheral functionalization of
porphyrins were developed. Particularly interesting are those involving the modification of β …

Reaction of known meso-tetraarylporpholactone free bases 3, made from the corresponding
porphyrins, with hydrazine produces three products: It converts the lactone functional group …

Recent scientific publications demonstrate a new approach to modeling catalysts that mimic
heme-containing enzymes. It involves the use of μ-oxo, μ-nitrido, and μ-carbido dimeric …

The reaction of β‐octaalkylporphyrins (octaethylporphyrin and etioporphyrin I) with ozone
generated the corresponding heptaalkyloxazolochlorinhemiacetals in which a pyrrolic …

The conversion of meso-aryl-porphyrins/chlorins to porphyrinoids containing nonpyrrolic
heterocycles (so-called pyrrole-modified porphyrins, PMPs) along an approach we dubbed …

While the 'breaking and mending of porphyrin strategy'proved versatile in the generation of a
range of pyrrole-modified porphyrins containing 4-, 5-, and 6-membered heterocycles, it …