All-inorganic POM cages and their assembly: A review

Q Lai, XX Li, ST Zheng - Coordination Chemistry Reviews, 2023 - Elsevier
Searching for suitable methods to construct all-inorganic cage materials by using
polyoxometalates (POMs) as secondary building units (SBUs) has been of great interest …

Bio-Inspired Iron-Based Carbonic Anhydrase Mimic for CO2 Hydration and Conversion

F Zhu, H Qiu, F Wang, X Zhang, GP Lu… - ACS Sustainable …, 2023 - ACS Publications
CO2 conversion by stable, cost-effective carbonic anhydrase (CA)-like nanozymes emerges
as an efficient and sustainable approach for CO2 fixation. In this work, a novel iron-based …

Substrate-assisted carbon dioxide activation as a versatile approach for heterocyclic synthesis

J Rintjema, AW Kleij - Synthesis, 2016 - thieme-connect.com
The incorporation of CO 2 into substrates containing alcohol or amine functional groups
displays interesting substrate-controlled reactivity, both in terms of providing milder reaction …

Biomimetic Catalysis of CO2 Hydration: A Materials Perspective

M Verma, GA Bhaduri, VS Phani Kumar… - Industrial & …, 2021 - ACS Publications
Rising temperatures and changing weather patterns have made the effect of climate change
more evident setting up an alarm for the need of quick action for its mitigation. Carbon …

A Molecular CO2 Reduction Catalyst Based on Giant Polyoxometalate {Mo368}

S Das, T Balaraju, S Barman, SS Sreejith… - Frontiers in …, 2018 - frontiersin.org
Photocatalytic CO2 reduction in water is one of the most attractive research pursuits of our
time. In this article we report a giant polyoxometalate {Mo368} based homogeneous catalytic …

Carbonic Anhydrase-Mimicking Keplerate Cluster Encapsulated Iron Trimesate for Base-Free CO2 Hydrogenation

KR Oh, Y Han, GY Cha, AH Valekar… - ACS Sustainable …, 2021 - ACS Publications
Producing formic acid (FA) via base-free CO2 hydrogenation suffers from low conversion
efficiency because of the difficulty of activating CO2 and the low solubility of CO2 in neutral …

Molecular-scale co-assembly membranes derived from keplerate cluster: carbonic anhydrase-mimicking nanocapsules for enhanced CO2/N2 separation

WL Zhao, H Li, R Zheng, Y Yang, W Chen… - Science China …, 2024 - Springer
The development of CO2 separation membranes with high permeability and high selectivity,
as well as ultra-thin selective layers, has always been challenging. Herein, a molecular …

Comprehensive Review and Perspectives of CO2 Hydrate Storage in Subseafloor Saline Sediments: Formation, Stability, and Optimization Strategies

EE Kasala, N Fang, J Wang, W Hussain - Energy & Fuels, 2024 - ACS Publications
Exploring various strategies for CO2 hydrate storage in subseafloor saline sediments
reveals a promising yet challenging path toward mitigating anthropogenic CO2 emissions …

Bicarbonate inhibition of carbonic anhydrase mimics hinders catalytic efficiency: elucidating the mechanism and gaining insight toward improving speed and efficiency

JGD Rains, K O'Donnelly, T Oliver, R Woscholski… - ACS …, 2019 - ACS Publications
Carbonic anhydrase (CA) mimics are often studied with a focus on the hydration of CO2 for
atmospheric carbon capture. Consequently, the reverse reaction (dehydration of HCO3–) …

Advances in gigantic polyoxomolybdate chemistry

DL Long, L Cronin - Advances in Inorganic Chemistry, 2021 - Elsevier
Since 1996 when Müller et al. determined the first giant Molybdenum Blue (MB) wheel {Mo
154} and revealed the 200-year-old mystery, many hundreds of compounds of this type and …