Multicomponent reactions and photo/electrochemistry join forces: atom economy meets energy efficiency

GA Coppola, S Pillitteri, EV Van der Eycken… - Chemical Society …, 2022 - pubs.rsc.org
Visible-light photoredox catalysis has been regarded as an extremely powerful tool in
organic chemistry, bringing the spotlight back to radical processes. The versatility of …

Applications of Photoredox Catalysis for the Radical-Induced Cleavage of C–C Bonds

J Vanderghinste, S Das - Synthesis, 2022 - thieme-connect.com
Selective cleavage of C–C bonds forms one of the greatest challenges in current organic
chemistry, due to the relative strength of these bonds. However, such transformations are an …

Photocatalytic Visible-Light-Induced Nitrogen Insertion via Dual C(sp3)–H and C(sp2)–H Bond Functionalization: Access to Privileged Imidazole-based Scaffolds

SM Patel, EP P, M Bakthadoss, DS Sharada - Organic Letters, 2020 - ACS Publications
Here we have demonstrated a visible-light-mediated metal-free organic-dye-catalyzed
dehydrogenative N-insertion leading to highly substituted imidazoles and privileged …

Copper‐Mediated Synthesis of N‐Aryl‐Oxamic Acids

M Badufle, F Robert, Y Landais - Chemistry–A European …, 2024 - Wiley Online Library
Abstract The Cu‐catalyzed Ullmann‐Goldberg cross‐coupling between aryl iodides and
oxamates is shown to afford the corresponding N‐aryloxamates with yields ranging from …

t-BuOOH/TiO2 Photocatalytic System as a Convenient Peroxyl Radical Source at Room Temperature under Visible Light and Its Application for the CH-Peroxidation …

ER Lopat'eva, IB Krylov, AO Terent'ev - Catalysts, 2023 - mdpi.com
TiO2 is one of the most promising heterogeneous photoredox catalysts employed in
oxidative pollutant destruction, CO2 reduction, water splitting, disinfection, solar cell design …

Electrochemical esterification reaction of alkynes with diols via cleavage of carbon–carbon triple bonds without catalyst and oxidant

PL Wang, HZ Shen, HH Cheng, H Gao, PH Li - Green Chemistry, 2020 - pubs.rsc.org
A novel electrochemical esterification of alkynes for the synthesis of esters was developed in
which diols and their derivatives were used as the partners. This method is green as it is …

Aerobic Photoredox Catalyzed Oxamate Ester Synthesis from Bromodifluoroacetate Esters

T Tagami, S Kawamura… - European Journal of …, 2024 - Wiley Online Library
Here we report an aerobic photoredox catalysis approach to oxamate ester synthesis using
bromodifluoroacetate esters and amines under open‐air conditions. Oxamate ester is an …

Base‐Promoted Difunctionalization of Alkynes: One‐Pot Synthesis of Polysubstituted Chromones

M Wang, L Cheng, J Ma, W Lu… - European Journal of …, 2023 - Wiley Online Library
A transition‐metal‐free one‐pot procedure for the difunctionalization of alkynes by C− C
triple bond oxidation and transformation towards chromone derivatives has been developed …

Advances in Carbon‐Carbon Bond Activation by Using Photocatalysts: A Mini Review

TT Pham - ChemistrySelect, 2022 - Wiley Online Library
Over the past decades, C− C bond activation has been an attractive area in organic
synthesis due to its power in construction of complexed molecules. This review covers …

[PDF][PDF] 炔烃与二醇通过碳-碳叁键裂解的电化学酯化反应

唐海涛, 潘英明 - Chin. J. Org. Chem, 2021 - academia.edu
碳-碳键的裂解反应作为一种有用的合成工具可用于构建许多有价值的化合物,
该类反应目前受到了许多关注, 并在农药, 药物和材料领域得到了广泛应用[1] …