Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Intra-cluster growth meets inter-cluster assembly: The molecular and supramolecular chemistry of atomically precise nanoclusters

X Kang, M Zhu - Coordination Chemistry Reviews, 2019 - Elsevier
The molecular and supramolecular chemistry of atomically precise nanoclusters
encompasses intra-cluster growth, inter-cluster assembly, and cluster-based host-guest …

Molecule-like synthesis of ligand-protected metal nanoclusters

Q Yao, M Zhu, Z Yang, X Song, X Yuan… - Nature Reviews …, 2024 - nature.com
Ligand-protected metal nanoclusters (NCs) are ultrasmall particles (< 3 nm) that represent
the molecular state of metal materials. Owing to their molecule-like structure—particularly …

Cd atom goes into the interior of cluster induced by directional consecutive assembly of tetrahedral units on an icosahedron kernel

Y Tan, Y Lv, L Xu, Q Li, J Chai, S Yang… - Journal of the …, 2023 - ACS Publications
“Core sliding” in metal nanoclusters drives the reconstruction of external structural units and
provides an ideal platform for mapping their precise transformation mechanism and …

Disc‐Like Silver Nanocluster Ag93 Built with Bicapped Hexagonal Prismatic Ag15 and Ino Decahedral Ag13 Units

F Hu, RL He, ZJ Guan, CY Liu… - Angewandte Chemie, 2023 - Wiley Online Library
The reduction of alkynyl‐silver and phosphine‐silver precursors with a weak reducing
reagent Ph2SiH2 led to the formation of a novel silver nanocluster [Ag93 (PPh3) 6 (C≡ CR) …

Toward the creation of high-performance heterogeneous catalysts by controlled ligand desorption from atomically precise metal nanoclusters

T Kawawaki, Y Kataoka, M Hirata, Y Iwamatsu… - Nanoscale …, 2021 - pubs.rsc.org
Ligand-protected metal nanoclusters controlled by atomic accuracy (ie atomically precise
metal NCs) have recently attracted considerable attention as active sites in heterogeneous …

Atomically precise copper dopants in metal clusters boost up stability, fluorescence, and photocatalytic activity

Y Zhang, J Zhang, Z Li, Z Qin, S Sharma… - Communications …, 2023 - nature.com
The structurally precise alloy nanoclusters have been emerged as a burgeoning
nanomaterial for their unique physical/chemical features. We here report a rod-like …

Atomically precise alloy nanoclusters

T Kawawaki, Y Imai, D Suzuki, S Kato… - … A European Journal, 2020 - Wiley Online Library
Metal nanoclusters (NCs) have a particle size of about one nanometer, which makes them
the smallest unit that can give a function to a substance. In addition, metal NCs possess …

Staggered Assembly of a Dimeric Au13 Cluster: Impacts on Coupling of Geometric Isomerism

JS Yang, YJ Zhao, XM Li, XY Dong… - Angewandte Chemie …, 2024 - Wiley Online Library
The specific states of aggregation of metal atoms in sub‐nanometer‐sized gold clusters are
related to the different quantum confinement volumes of electrons, leading to novel optical …