Recent developments in chemistry of hypervalent organoantimony and-bismuth complexes
with bidentate (C, E)-and tridentate (E, C, E)-and (C, E, C)-ligands are reviewed. The ligands …

This short review article provides an insight into the synthetic chemistry involved in the
formation of bismuth based versatile frameworks. A unique feature of bismuth compounds is …

One on one: A combination of steric effects and M N interactions of a rigid NCN pincer
ligand allows the isolation and characterization of monomeric stibinidene and …

This study, which aims to identify atypical platforms for the reduction of dioxygen, describes
the reaction of O2 with two distibines, namely, 4, 5-bis (diphenylstibino)-2, 7-di-tert-butyl-9, 9 …

Stibinyl and bismuthinyl radicals are recognized as representative intermediates of antimony
and bismuth compounds, but still elusive in the condensed phase. We successfully …

The isolation of simple, fundamentally important, and highly reactive organometallic
compounds remains among the most challenging tasks in synthetic chemistry. The detailed …

The reactions of the organoantimony (I) compound L14Sb4 (1)(where L1=[o-C6H4 (CH
NC6H3 (i-Pr) 2-2, 6)]) with diphenyldichalcogenides PhEEPh (E= S, Se, or Te) gave …

Two new bismuth (III) complexes,[BiL 1 Cl 2](1) and [BiL 2 Cl 2](2), in which L 1 is (2-hydroxy-
4-6-di-tert-butylbenzyl-2-pyridylmethyl) amine and L 2 is 2, 4-diiodo-6-((pyridine-2 …

Organometallic Lewis acids play an important role in modern organic synthesis. How to
design and synthesize highly efficient and recyclable organometallic Lewis acid catalysts …

The synthesis, transformation, and application in catalysis of triphenyllead hydroperoxide,
the first dioxygen lead complex, are described. Triphenyllead hydroperoxide is …