Activation and reduction of O2 and H2O2 by synthetic and biosynthetic iron porphyrin
models have proved to be a versatile platform for evaluating second-sphere effects deemed …

The search for new catalytic materials has relied on highly time-and human-resource-
consuming procedures. The appearance of theoretical methods that employ density …

An environmentally benign, sustainable, and cost-effective supply of H2O2 as a rapidly
expanding consumption raw material is highly desired for chemical industries, medical …

Oxygen reduction reaction (ORR) is an important process involved in natural and artificial
energy conversion schemes. As inspired by cytochrome c oxidases (CcOs), which are …

We report a supramolecular strategy for promoting the selective reduction of O2 for direct
electrosynthesis of H2O2. We utilized cobalt tetraphenylporphyrin (Co‐TPP), an oxygen …

The challenge of activating inert C–H bonds motivates a study of catalysts that draws from
what can be accomplished by natural enzymes and translates these advantageous features …

In situ synthesis of reactive oxygen species (ROS) on demand via oxygen activation (OA) is
significant in biological, chemical, and environmental fields. Thus, the design of OA catalysts …

The reduction of dioxygen (O2) is of vital importance to energy-related reactions. In biology,
respiration uses O2 reduction as a thermodynamic sink, whereas fuel cells pair the oxygen …

Surface immobilized catalysts are highly promising candidates for a range of energy
conversion reactions, and atomistic mechanistic understanding is essential for their rational …

A cobalt porphyrin complex with a pendant imidazole base ([(L1) CoII]) is an efficient catalyst
for the homogeneous catalytic two‐electron reduction of dioxygen by 1, 1 …