Trivalent europium–a scarce case in intermetallics

S Engel, ECJ Gießelmann, R Pöttgen… - Reviews in Inorganic …, 2023 - degruyter.com
In most intermetallic europium compounds, the Eu atoms exhibit a divalent oxidation state
with a high effective magnetic moment since Eu2+ is isoelectronic with Gd3+. Trivalent …

Coloring in the ZrBeSi-type structure

SF Matar, R Pöttgen - Zeitschrift für Naturforschung B, 2019 - degruyter.com
The ZrBeSi type is a superstructure variant of the aristotype AlB2 with an ordering of the
beryllium and silicon atoms on the boron network. Every other layer of Be3Si3 hexagons is …

Anisotropic hybridization in CeRhSn

TU Böhm, NS Sirica, BG Jang, Y Liu, ED Bauer… - Physical Review B, 2024 - APS
The optical conductivity σ (ω, T) of CeRhSn was studied by broadband infrared
spectroscopy. Temperature-dependent spectral weight transfer occurs over high energy (0.8 …

Synthesis, magnetic and NMR spectroscopic properties of the MAl 5 Pt 3 series (M= Ca, Y, La–Nd, Sm–Er)

S Engel, ECJ Gießelmann, L Schumacher… - Dalton …, 2024 - pubs.rsc.org
Following recent investigation in the ternary system Sr–Al–Pt led to the discovery of SrAl5Pt3
which crystallizes in the orthorhombic YNi5Si3 type (Pnma) structure. Interestingly, only two …

Interplay between Kondo and magnetic interactions in Pr0. 75Gd0. 25ScGeH

T Del Rose, R Choudhary, Y Mudryk, D Haskel… - Journal of Alloys and …, 2023 - Elsevier
Combined experimental and density functional theory (DFT) study of Pr 0.75 Gd 0.25 ScGe
and its hydride (Pr 0.75 Gd 0.25 ScGeH) reveals intricacies of composition-structure …

Crystal, Magnetic Structures, and Bonding Interactions in the TiNiSi-Type Hydride CeMgSnH: Experimental and Computational Studies

VA Yartys, LG Akselrud, RV Denys… - Chemistry of …, 2024 - ACS Publications
By combining experimental and computational studies, the orthorhombic stannide CeMgSn
with a TiNiSi-type structure has been characterized as a potential hydrogen storage …

Hydrogen impact on magnetic properties of metallic systems

L Havela - Journal of Alloys and Compounds, 2022 - Elsevier
A brief overview of the impact of presence of hydrogen in metallic systems on magnetic
properties is given. Respective differences between the 4 f, 5f, and 3d system are …

Origins of magnetic memory and strong exchange bias bordering magnetic compensation in mixed-lanthanide systems

TJ Del Rose, Y Mudryk, D Haskel, AK Pathak… - Physical Review …, 2022 - APS
Unexpected physical phenomena resulting from the seemingly inconsequential substitutions
of chemically similar lanthanide elements in the Pr 1− x Gd x ScGe system are exploited to …

Correlations of Crystal and Electronic Structure via NMR and X-ray Photoelectron Spectroscopies in the RETMAl2 (RE = Sc, Y, La–Nd, Sm, Gd–Tm, Lu; TM = Ni, Pd …

M Radzieowski, F Stegemann, C Doerenkamp… - Inorganic …, 2019 - ACS Publications
A total of 35 intermetallic aluminum compounds have been synthesized from the elements
via arc melting and characterized by powder X-ray diffraction. A total of 15 of them have …

Easy-plane ferromagnetic ordering and crystal-field ground state in the Kondo lattice CeCuSi

H Jin, O Moulding, JC Fettinger, Y Gao, P Klavins… - Physical Review B, 2024 - APS
We report the successful growth of CeCuSi single crystals using a metallic flux method and
the physical properties using structural, magnetic, electrical transport, optical, and heat …