The Marcus inverted region

P Suppan - Photoinduced Electron Transfer IV, 2005 - Springer
Abstract The “Marcus Inverted Region”(MIR) is that part of the function of rate constant
versus free energy where a chemical reaction becomes slower as it becomes more …

Photoinduced hydrogen atom abstraction by carbonyl compounds

P Wagner, BS Park - Organic photochemistry, 2017 - taylorfrancis.com
Hydrogen atom abstraction by photoexcited carbonyl compounds has played a central role
in the development of a general picture of how photochemical reactions occur …

Salt effects resulting from exchange between two ion pairs and their crucial role in reaction

A Loupy, B Tchoubar, D Astruc - Chemical reviews, 1992 - ACS Publications
Ion pairing is an essential featureof the medium-dependent reactivity inmolecular chemistry.
In par-ticular the presence of a salt in a reaction medium involving an ion pair brings about a …

Comparison of DNA Damage Photoinduced by Ketoprofen, Fenofibric Acid and Benzophenone via Electron and Energy Transfer¶

V Lhiaubet, N Paillous… - Photochemistry and …, 2001 - Wiley Online Library
Ketoprofen (KP) and fenofibrate, respectively, anti‐inflammatory and hypolipidemiant
agents, promote anormal photosensitivity in patients and may induce photoallergic cross …

Photoinduced electron transfer reactions of amines: synthetic applications and mechanistic studies

JSD Kumar, S Das - Research on chemical intermediates, 1997 - Springer
Fundamental aspects of photoinduced electron transfer processes have received
considerable attention in recent years in view of their relevance to a number of important …

Absolute Kinetics of Aminium Radical Reactions with Olefins in Acetonitrile Solution1

BD Wagner, G Ruel, J Lusztyk - Journal of the American Chemical …, 1996 - ACS Publications
Photolysis of N-nitrosamines in acidic acetonitrile produces aminium radical cations via
protonation of the initially-formed aminyl radicals. The kinetics of these species can be …

UV—vis absorption studies of singlet to triplet intersystem crossing rates of aromatic ketones: effects of molecular geometry

PF McGarry, CE Doubleday Jr, CH Wu… - … of Photochemistry and …, 1994 - Elsevier
The effect of the molecular geometry of diaryl and arylalky ketones on the rate of intersystem
crossing (ISC) was investigated by employing picosecond pump—probe studies of the …

Ultrafast study of substituted-position-dependent excited-state evolution in benzophenone-carbazole dyads

J Li, S Yang, Z Deng, S Ni, S Chen… - Physical Chemistry …, 2022 - pubs.rsc.org
Donor and acceptor (D–A) compounds based on benzophenone (BP) and carbazole (Cz)
were recently reported to exhibit an extraordinary long afterglow phosphorescence in the …

Photolytic Release of Carboxylic Acids Using Linked Donor−Acceptor Molecules:  Direct versus Mediated Photoinduced Electron Transfer to N-Alkyl-4-picolinium …

C Sundararajan, DE Falvey - Organic Letters, 2005 - ACS Publications
Efficient photorelease (Φ= 0.7) of carboxylic acids is achieved with a covalently linked
mediator (benzophenone) protecting group (N-alkyl-4-picolinium ester) molecule. The …

Picosecond dynamics of the photoreduction of benzophenone by DABCO

KS Peters, J Lee - The Journal of Physical Chemistry, 1993 - ACS Publications
Picosecond absorption spectroscopy is used to examine the dynamics of the quenching of
the first excited singlet and triplet states of benzophenone by 1, 4-diazabicyclo [2.2. 2] …