Impact of Surface Enhanced Raman Spectroscopy in Catalysis

A Stefancu, J Aizpurua, I Alessandri, I Bald… - ACS …, 2024 - ACS Publications
Catalysis stands as an indispensable cornerstone of modern society, underpinning the
production of over 80% of manufactured goods and driving over 90% of industrial chemical …

Integrating, Validating, and Expanding Information Space in Single-Molecule Surface-Enhanced Raman Spectroscopy for Biomolecules

Y Lee, K Choi, JE Kim, S Cha, JM Nam - ACS nano, 2024 - ACS Publications
Single-molecule surface-enhanced Raman spectroscopy (SM-SERS) is an ultrahigh-
resolution spectroscopic method for directly obtaining the complex vibrational mode …

Picocavities: a primer

JJ Baumberg - Nano Letters, 2022 - ACS Publications
Picocavities are sub-nanometer-scale optical cavities recently found to trap light, which are
formed by single-atom defects on metallic facets. Here, we develop simple picocavity …

Giant optomechanical spring effect in plasmonic nano-and picocavities probed by surface-enhanced Raman scattering

LA Jakob, WM Deacon, Y Zhang, B de Nijs… - Nature …, 2023 - nature.com
Molecular vibrations couple to visible light only weakly, have small mutual interactions, and
hence are often ignored for non-linear optics. Here we show the extreme confinement …

Optical suppression of energy barriers in single molecule-metal binding

Q Lin, S Hu, T Földes, J Huang, D Wright, J Griffiths… - Science …, 2022 - science.org
Transient bonds between molecules and metal surfaces underpin catalysis, bio/molecular
sensing, molecular electronics, and electrochemistry. Techniques aiming to characterize …

Atomically smooth single-crystalline platform for low-loss plasmonic nanocavities

L Liu, AV Krasavin, J Zheng, Y Tong, P Wang, X Wu… - Nano Letters, 2022 - ACS Publications
Nanoparticle-on-mirror plasmonic nanocavities, capable of extreme optical confinement and
enhancement, have triggered state-of-the-art progress in nanophotonics and development …

Manipulating Quantum Interference between σ and π Orbitals in Single-Molecule Junctions via Chemical Substitution and Environmental Control

HE Skipper, B Lawson, X Pan, V Degtiareva… - ACS …, 2023 - ACS Publications
Understanding and manipulating quantum interference (QI) effects in single molecule
junction conductance can enable the design of molecular-scale devices. Here we …

Locating single-atom optical picocavities using wavelength-multiplexed Raman scattering

J Griffiths, B De Nijs, R Chikkaraddy… - ACS …, 2021 - ACS Publications
Transient atomic protrusions in plasmonic nanocavities confine optical fields to sub-1-nm3
picocavities, allowing the optical interrogation of single molecules at room temperature …

A 4D x-ray computer microtomography for high-temperature electrochemistry

H Jiao, Z Qu, S Jiao, Y Gao, S Li, WL Song, H Chen… - Science …, 2022 - science.org
High-temperature electrochemistry is widely used in many fields. However, real-time
observations and an in-depth understanding of the inside evolution of this system from an …

Optical spectroscopy of surfaces, interfaces, and thin films

TJ Blackburn, SM Tyler, JE Pemberton - Analytical Chemistry, 2022 - ACS Publications
Efforts to characterize solid/liquid, solid/gas, liquid/gas, liquid/liquid, and liquid/gas
interfaces utilizing optical spectroscopies in the ultraviolet− visible (UV− vis), infrared (IR) …