The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

A Simple and Highly Efficient Iron Catalyst for a [2+2+2] Cycloaddition to Form Pyridines ×
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The rapid generation of molecular in a relatively easy manner has made the cycloaddition
reaction a powerful tool in the synthesis of different membered ring compounds. Clearly, iron …

Efficient iron‐catalyzed homocoupling of terminal alkynes and cross‐dimerization of aryl
acetylenes with trimethylsilylacetylene is reported. The complex [Fe (H)(BH4)(iPr‐PNP)](1) …

An iron-catalyzed [2+ 2+ 2] cycloaddition reaction of diynes and cyanamides at room
temperature is reported. Highly substituted 2-aminopyridines were obtained in good to …

The development of pyrimidine-based analogues of the well-known pyridinediimine (PDI)
iron complexes enables access to a functional-group-tolerant methodology for the catalytic …

Adaptive ligands, which can adapt their coordination mode to the electronic structure of
various catalytic intermediates, offer the potential to develop improved homogeneous …

Catalyzing C− C bond‐forming reactions with earth‐abundant metals under mild conditions
is at the heart of sustainable synthesis. The cyclotrimerization of alkynes is a valuable atom …

Diynes and cyanamides undergo an iron-catalyzed [2+ 2+ 2] cycloaddition to form highly
substituted 2-aminopyridines in an atom-efficient manner that is both high yielding and …

Iron complexes bound by redox-active pyridine dialdimine (PDAI) ligands catalyze the
cycloaddition of two terminal alkynes and one cyanamide. The reaction is both chemo-and …