Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Water-stable metal–organic frameworks (MOFs): rational construction and carbon dioxide capture

C Xiao, J Tian, Q Chen, M Hong - Chemical Science, 2024 - pubs.rsc.org
Metal–organic frameworks (MOFs) are considered to be a promising porous material due to
their excellent porosity and chemical tailorability. However, due to the relatively weak …

Defined metal atom aggregates precisely incorporated into metal–organic frameworks

KL Kollmannsberger, L Kronthaler… - Chemical Society …, 2022 - pubs.rsc.org
Nanosized metal aggregates (MAs), including metal nanoparticles (NPs) and nanoclusters
(NCs), are often the active species in numerous applications. In order to maintain the active …

[HTML][HTML] 3D electron diffraction as an important technique for structure elucidation of metal-organic frameworks and covalent organic frameworks

Z Huang, ES Grape, J Li, AK Inge, X Zou - Coordination Chemistry Reviews, 2021 - Elsevier
Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have emerged
as the most widely investigated classes of porous materials during the past two decades …

Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

JH Lee, S Jeoung, YG Chung, HR Moon - Coordination Chemistry Reviews, 2019 - Elsevier
Flexibility is a unique property of metal-organic frameworks (MOFs) that differentiates them
from other rigid inorganic porous materials such as zeolites and porous silica. Flexible …

Controlling Cooperative CO2 Adsorption in Diamine-Appended Mg2(dobpdc) Metal–Organic Frameworks

RL Siegelman, TM McDonald… - Journal of the …, 2017 - ACS Publications
In the transition to a clean-energy future, CO2 separations will play a critical role in
mitigating current greenhouse gas emissions and facilitating conversion to cleaner-burning …

Pore surface engineering of metal–organic frameworks for heterogeneous catalysis

Y Wen, J Zhang, Q Xu, XT Wu, QL Zhu - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Metal–organic frameworks (MOFs), a class of emerging crystalline porous
materials, have received great attention for their prospective applications in various areas. In …

Atomic/molecular layer deposition for designer's functional metal–organic materials

J Multia, M Karppinen - Advanced Materials Interfaces, 2022 - Wiley Online Library
Atomic layer deposition (ALD) for high‐quality conformal inorganic thin films is one of the
cornerstones of modern microelectronics, while molecular layer deposition (MLD) is its less …

M2(m-dobdc) (M = Mn, Fe, Co, Ni) Metal–Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations

JE Bachman, MT Kapelewski, DA Reed… - Journal of the …, 2017 - ACS Publications
The metal–organic frameworks M2 (m-dobdc)(M= Mn, Fe, Co, Ni; m-dobdc4–= 4, 6-dioxido-
1, 3-benzenedicarboxylate) were evaluated as adsorbents for separating olefins from …

Selective nitrogen adsorption via backbonding in a metal–organic framework with exposed vanadium sites

DE Jaramillo, DA Reed, HZH Jiang, J Oktawiec… - Nature materials, 2020 - nature.com
Industrial processes prominently feature π-acidic gases, and an adsorbent capable of
selectively interacting with these molecules could enable important chemical separations …