Two‐Electron Redox Reactivity of Thorium Supported by Redox‐Active Tripodal Frameworks
FC Hsueh, D Chen, T Rajeshkumar… - Angewandte …, 2024 - Wiley Online Library
The high stability of the+ IVoxidation state limits thorium redox reactivity. Here we report the
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …
Intrinsic Reactivity of [η5-1,3-(Me3C)2C5H3]2Th(bipy) toward Small Molecules
D Wang, Y Heng, T Li, G Zi, MD Walter - Organometallics, 2024 - ACS Publications
The reactivity of the thorium bipyridyl metallocene (Cp2 t Bu) 2Th (bipy)(1; Cp2 t Bu= η 5-1, 3-
(Me3C) 2C5H3) toward a series of small molecules was explored, and the emerging …
(Me3C) 2C5H3) toward a series of small molecules was explored, and the emerging …
Influence of 1,2,4-Tri-tert-butylcyclopentadienyl Ligand on the Reactivity of the Thorium Bipyridyl Metallocene [η5-1,2,4-(Me3C)3C5H2]2Th(bipy)
D Wang, Y Heng, T Li, W Ding, G Hou, G Zi… - Inorganic …, 2024 - ACS Publications
The thorium bipyridyl metallocene (Cp3 t Bu) 2Th (bipy)(1; Cp3 t Bu= η5-1, 2, 4-(Me3C)
3C5H2) shows a rich reactivity toward a series of small molecules. For example, complex 1 …
3C5H2) shows a rich reactivity toward a series of small molecules. For example, complex 1 …
N-Aryloxide-Amidinate Thorium Complexes
An N-aryloxide-amidine ligand (1),[ONNO] ligand, integrating phenoxide (PhO–) and
amidine ligands through methylene linkers, was employed in actinide chemistry. Upon …
amidine ligands through methylene linkers, was employed in actinide chemistry. Upon …
Synthesis and Structure of [η5-1,2,4-(Me3Si)3C5H2]2Th(bipy) and Its Reactivity toward Small Molecules
S Wang, D Wang, Y Heng, T Li, W Ding, G Zi… - Inorganic …, 2024 - ACS Publications
Halide exchange of (Cp3tms) 2ThCl2 (1; Cp3tms= η5-1, 2, 4-(Me3Si) 3C5H2) with Me3SiI
furnishes (Cp3tms) 2ThI2 (2), which is then reduced with potassium graphite (KC8) in the …
furnishes (Cp3tms) 2ThI2 (2), which is then reduced with potassium graphite (KC8) in the …