Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties

J Li, M Gao, W Yan, J Yu - Chemical Science, 2023 - pubs.rsc.org
Zeolites are typically a class of crystalline microporous aluminosilicates that are constructed
by SiO4 and AlO4 tetrahedra. Because of their unique porous structures, strong Brönsted …

Atom probe tomography

B Gault, A Chiaramonti, O Cojocaru-Mirédin… - Nature Reviews …, 2021 - nature.com
Atom probe tomography (APT) provides three-dimensional compositional mapping with sub-
nanometre resolution. The sensitivity of APT is in the range of parts per million for all …

Confining isolated atoms and clusters in crystalline porous materials for catalysis

L Liu, A Corma - Nature Reviews Materials, 2021 - nature.com
Abstract Structure–reactivity relationships for nanoparticle-based catalysts have been
greatly influenced by the study of catalytic materials with either supported isolated metal …

Sequencing of metals in multivariate metal-organic frameworks

Z Ji, T Li, OM Yaghi - Science, 2020 - science.org
We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-
organic framework–74 containing mixed combinations of cobalt (Co), cadmium (Cd), lead …

Carbon deposit analysis in catalyst deactivation, regeneration, and rejuvenation

ETC Vogt, D Fu, BM Weckhuysen - … Chemie International Edition, 2023 - Wiley Online Library
Hydrocarbon conversion catalysts suffer from deactivation by deposition or formation of
carbon deposits. Carbon deposit formation is thermodynamically favored above 350° C …

Elucidating the structure and composition of individual bimetallic nanoparticles in supported catalysts by atom probe tomography

F Zand, SJT Hangx, CJ Spiers… - Journal of the …, 2023 - ACS Publications
Understanding and controlling the structure and composition of nanoparticles in supported
metal catalysts are crucial to improve chemical processes. For this, atom probe tomography …

[HTML][HTML] Insight into hydrothermal aging effect on Pd sites over Pd/LTA and Pd/SSZ-13 as PNA and CO oxidation monolith catalysts

A Wang, K Lindgren, M Di, D Bernin… - Applied Catalysis B …, 2020 - Elsevier
In this study, Pd/LTA and Pd/SSZ-13 were prepared and then hydrothermally aged at the
temperature of 750, 800, 850, and 900° C. Multiple Pd species, including isolated Pd ions …

Tracking the rearrangement of atomic configurations during the conversion of FAU zeolite to CHA zeolite

K Muraoka, Y Sada, A Shimojima, W Chaikittisilp… - Chemical …, 2019 - pubs.rsc.org
In order to realize designed synthesis, understanding the formation mechanism of zeolites at
an atomic level has long been aspired, but remains challenging due to the fact that the …

Acidity enhancement through synergy of penta-and tetra-coordinated aluminum species in amorphous silica networks

Z Wang, T Li, Y Jiang, O Lafon, Z Liu, J Trébosc… - Nature …, 2020 - nature.com
Amorphous silica-aluminas (ASAs) are widely used in acid-catalyzed CH activation
reactions and biomass conversions in large scale, which can be promoted by increasing the …

A review of recent developments for the in situ/operando characterization of nanoporous materials

H Petersen, C Weidenthaler - Inorganic Chemistry Frontiers, 2022 - pubs.rsc.org
This is a review on up-to-date in situ/operando methods for a comprehensive
characterization of nanoporous materials. The group of nanoporous materials is constantly …