Hypervalent organoantimony and-bismuth compounds with pendant arm ligands

CI Raţ, C Silvestru, HJ Breunig - Coordination Chemistry Reviews, 2013 - Elsevier
Recent developments in chemistry of hypervalent organoantimony and-bismuth complexes
with bidentate (C, E)-and tridentate (E, C, E)-and (C, E, C)-ligands are reviewed. The ligands …

Organobismuth reagents: synthesis, properties and applications in organic synthesis

A Gagnon, J Dansereau, A Le Roch - Synthesis, 2017 - thieme-connect.com
Organobismuth compounds are organometallic reagents that contain a C–Bi bond. These
species, which are easily accessed from inexpensive and low-toxicity inorganic bismuth …

Synthesis of highly functionalized triarylbismuthines by functional group manipulation and use in palladium-and copper-catalyzed arylation reactions

M Hébert, P Petiot, E Benoit, J Dansereau… - The Journal of …, 2016 - ACS Publications
Organobismuthines are an attractive class of organometallic reagents that can be accessed
from inexpensive and nontoxic bismuth salts. Triarylbismuthines are particularly interesting …

Synthesis, properties characterization and applications of various organobismuth compounds

J Luan, L Zhang, Z Hu - Molecules, 2011 - mdpi.com
Organobismuth chemistry was emphasized in this review article due to the low price, low
toxicity and low radioactivity characteristics of bismuth. As an environmentally-friendly class …

Synthesis and structure of an air-stable organobismuth triflate complex and its use as a high-efficiency catalyst for the ring opening of epoxides in aqueous media with …

N Tan, S Yin, Y Li, R Qiu, Z Meng, X Song, S Luo… - Journal of …, 2011 - Elsevier
An air-stable organobismuth triflate complex with a novel 5, 6, 7, 12-tetrahydrodibenzo [c, f]-
[1, 5] oxabismocine framework was synthesized and characterized by spectroscopic and …

Organobismuth compounds with the pincer ligand 2, 6-(Me 2 NCH 2) 2 C 6 H 3: Monoorganobismuth (iii) carbonate, sulfate, nitrate, and a diorganobismuthenium (iii) …

HJ Breunig, MG Nema, C Silvestru, AP Soran… - Dalton …, 2010 - pubs.rsc.org
The reaction of RBiCl2 (1)[R= 2, 6-(Me2NCH2) 2C6H3] with Na2CO3 or Ag2SO4 (1: 1 molar
ratio) gave RBiCO3 (2) and RBiSO4 (3), respectively. RBi (NO3) 2 (4) was obtained from …

Crystal structure, antibacterial and cytotoxic activities of a new complex of bismuth (III) with sulfapyridine

IM Marzano, MS Franco, PP Silva, R Augusti… - Molecules, 2013 - mdpi.com
A new complex of Bi (III) and sulfapyridine was synthesized and characterized by elemental
analysis, atomic absorption spectrometry, conductivity analysis, electrospray ionization mass …

Dose-dependent effects of L-Arginine on PROP bitterness intensity and latency and characteristics of the chemical interaction between PROP and L-Arginine

M Melis, M Arca, MC Aragoni, T Cabras, C Caltagirone… - PloS one, 2015 - journals.plos.org
Genetic variation in the ability to taste the bitterness of 6-n-propylthiouracil (PROP) is a
complex trait that has been used to predict food preferences and eating habits. PROP tasting …

[2‐{E(CH2CH2)2NCH2}C6H4]nBiX3–n (E = O, NMe; X = Cl, Br, I; n = 1–3) and [2‐(Me2NCH2)C6H4]BiBr2 – New Hypervalent …

HJ Breunig, MG Nema, C Silvestru, A Soran, RA Varga - 2010 - Wiley Online Library
Abstract The homoleptic [2‐{E (CH2CH2) 2NCH2} C6H4] 3Bi [E= O (1), MeN (2)], the
chlorides [2‐{E (CH2CH2) 2NCH2} C6H4] 2BiCl [E= O (3), MeN (4)] and the dichlorides [2 …

2,6‐Diisopropylphenyl substituted Bismuth Halide and Interpnictogen Compounds

T Dunaj, M Egorycheva, A Arebi… - Zeitschrift für …, 2023 - Wiley Online Library
Herein, we report about the preparation of several new 2, 6‐diisopropylphenyl (Dipp)
substituted (halido‐) bismuthanes, namely, Dipp3Bi (1) and compounds of the form …