Using light to control matter has captured the imagination of scientists for generations, as
there is an abundance of photons at our disposal. Yet delivering photons beyond the surface …

Supramolecular networks often possess good dynamic features but suffer from low
mechanical properties. Supramolecular coordination complexes including metallacycles …

Coordination‐driven crosslinking networks with reversible and dynamic characteristics are
gaining increasing interest in diverse application fields. Herein, we use a coordination …

Herein, a series of face-capped (Tr2M3) 4L4 (Tr= cycloheptatrienyl cationic ring; M= metal;
L= organosulfur ligand) tetrahedral cages 1–3 functionalized with 12 appended crown ether …

Construction of supramolecular structures with internal functionalities is a promising
approach to build enzyme‐like cavities. The endo‐functionalized [Pd12L24] and [Pd2L4] …

Utilizing carbon dioxide (CO2) to make polycarbonates through the ring‐opening
copolymerization (ROCOP) of CO2 and epoxides valorizes and recycles CO2 and reduces …

Integrating the advantages of homogeneous and heterogeneous catalysis has proved to be
an optimal strategy for developing catalytic systems with high efficiency, selectivity, and …

Metal–organic cages/polyhedra (MOCs) are versatile building blocks for advanced polymer
networks with properties that synergistically blend those of traditional polymers and …

Supramolecular polymer networks contain non-covalent cross-links that enable access to
broadly tunable mechanical properties and stimuli-responsive behaviors; the incorporation …

Metal–organic cages are versatile supramolecular architectures, fulfilling various distinct
roles in the mediation of catalysed chemical reactions. M n L2 n cages have become …