Nanoscale electro-mechanical systems (NEMS) displaying piezoresistance offer unique
measurement opportunities at the sub-cellular level, in detectors and sensors, and in …

The alarming rise in superbugs that are resistant to drugs of last resort, including
vancomycin-resistant enterococci and staphylococci, has become a significant global health …

The solution-state fluxional behavior of bullvalene has fascinated physical organic and
supramolecular chemists alike. Little effort, however, has been put into investigating …

The synthesis and processing of π‐rich polymers found in novel electronics and textiles is
difficult because chain stiffness leads to low solubility and high thermal transitions. The …

Salt lakes are abundant in three crucial resources− lithium (Li), magnesium (Mg), and boron
(B). The separation efficiency of these resources is low, the excessive use of acid and the …

A fluxional bis‐monodentate ligand, based on the archetypal shape‐shifting molecule
bullvalene, self‐assembles with M2+ (M= Pd2+ or Pt2+) to produce a highly complex …

Dynamic, shapeshifting hydrocarbons have emerged as enabling frameworks across drug
discovery, materials science, and catalysis. Their employment, however, is often hampered …

Shape-shifting molecules such as bullvalene undergo rapid structural reorganizations via
degenerate Cope rearrangements. Here, we obtain accurate CCSD (T)/CBS barrier heights …

Here, we analyze the stereodynamic properties of bullvalenes using principal moments of
inertia and exit vector plots to draw comparisons with commonly used ring systems in …

In search for structural features that enable the control of the valence isomerization of the
fluxional bullvalene, a bullvalene‐bis (harmane) conjugate is identified that acts as chelating …