Highly ordered mesoporous carbons and silicas with ultralarge accessible pores have been
successfully synthesized by using laboratory-made poly (ethylene oxide)-b-polystyrene …

We have successfully synthesized NaX zeolite crystals with controlled sizes from 20 nm to
0.8 μm, using a novel organic-additive-free approach. We show that the NaX crystal size …

Pentacoordinated silicon units, SiO4/2F-, were found by solid-state NMR experiments in
various as-made high-silica zeolites (Beta, SSZ-23, ITQ-3, ITQ-4, ZSM-12, Silicalite-1) that …

The three-dimensional microporosity of zeolite frameworks have allowed their widespread
use in industry as heterogeneous catalysts, absorbents, and ion-exchangers. While the …

Iron phosphates are of interest because of rich crystal chemistry and practical applications.
New crystalline iron phosphates have been prepared in aqueous or predominantly …

The use of a novel mixed-valence pentavanadate phosphate cluster as a building block has
made possible the low-temperature hydrothermal self-assembly of the new three …

The reaction of a single amine phosphate, piperazine phosphate, with ZnII ions is shown to
yield a variety of open-framework metal phosphate structures. It is noteworthy that the …

A 3-D, open framework, mixed valence iron phosphate,[H3NCH2CH2NH3] 2 [Fe4O (PO4)
4]⊙ H2O, which contains organic ethylenediammonium dications in the framework voids …

A series of novel vanadium silicates with open-framework and microporous structures has
been synthesized under mild hydrothermal conditions. Ten distinct framework types have …

The design of new and interesting inorganic frameworks is an ongoing challenge in
materials sciences. New structures containing double-four-ring (D4R) units have recently …