Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Generation and trapping of nitrosocarbonyl intermediates

MG Memeo, P Quadrelli - Chemical reviews, 2017 - ACS Publications
The nitrosocarbonyls (R–CONO) are highly reactive species and remarkable intermediates
toward different synthetic targets. This review will cover a research area whose impact in …

Peroxidase-induced C–N bond formation via nitroso ene and Diels–Alder reactions

C Jäger, BJ Gregori, JAS Aho, M Hallamaa… - Green Chemistry, 2023 - pubs.rsc.org
The formation of new carbon–nitrogen bonds is indisputably one of the most important tasks
in synthetic organic chemistry. Here, nitroso compounds offer a highly interesting reactivity …

Aerobic C− N Bond Formation through Enzymatic Nitroso‐Ene‐Type Reactions

C Jäger, M Haase, K Koschorreck… - Angewandte Chemie …, 2023 - Wiley Online Library
The biocatalytic oxidation of acylated hydroxylamines enables the direct and selective
introduction of nitrogen functionalities by activation of allylic C− H bonds. Utilizing either …

Oxidative cyclization of sulfamates onto pendant alkenes

AH Shinde, S Sathyamoorthi - Organic letters, 2020 - ACS Publications
This communication discloses the first examples of aza-Wacker cyclizations of sulfamate
esters. Within the realm of related cyclization reactions, this protocol is differential in that it …

Organic dye‐photocatalyzed acylnitroso ene reaction

YC Teo, Y Pan, CH Tan - ChemCatChem, 2013 - Wiley Online Library
Rose bengal, an inexpensive and readily available organic dye, is demonstrated to be a
photoredox catalyst for the formation of transient acylnitroso intermediates under visible light …

Iron-catalyzed synthesis of heterocycles

KC Majumdar, N De, T Ghosh, B Roy - Tetrahedron, 2014 - Elsevier
Heterocycles are unquestionably important structural motifs and major building blocks of a
wide range of natural products. 1 These are useful as pharmaceuticals, agrochemicals …

Oxidative CO Cross‐Coupling of 1,3‐Dicarbonyl Compounds and Their Heteroanalogues with N‐Substituted Hydroxamic Acids and N‐Hydroxyimides

AO Terent'ev, IB Krylov, VP Timofeev… - Advanced Synthesis …, 2013 - Wiley Online Library
Abstract The oxidative C O cross‐coupling of 1, 3‐dicarbonyl compounds and their
heteroanalogues, 2‐substituted malononitriles and cyanoacetic esters, with N‐substituted …

Metal-free enantioselective hydroxyamination of aldehydes with nitrosocarbonyl compounds catalyzed by an axially chiral amine

T Kano, F Shirozu, K Maruoka - Journal of the American Chemical …, 2013 - ACS Publications
The first example of a highly regio-and enantioselective hydroxyamination of aldehydes with
in situ generated nitrosocarbonyl compounds from hydroxamic acid derivatives was realized …

Nitroso-azomethine (ene) reaction enabled annulations of nitrosoarenes, azomethines and alkenes

SV SingháPal - Chemical Communications, 2024 - pubs.rsc.org
An unprecedented example of a nitroso-azomethine (ene) reaction is reported. Nitroso-
azomethine (ene) reaction-mediated unprecedented annulation of nitrosoarenes …