3d-Metal catalyzed N-and C-alkylation reactions via borrowing hydrogen or hydrogen autotransfer

T Irrgang, R Kempe - Chemical reviews, 2018 - ACS Publications
The conservation of our element resources is a fundamental challenge of mankind. The
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …

Advances in one-pot synthesis through borrowing hydrogen catalysis

A Corma, J Navas, MJ Sabater - Chemical reviews, 2018 - ACS Publications
The borrowing hydrogen (BH) principle, also called hydrogen auto-transfer, is a powerful
approach which combines transfer hydrogenation (avoiding the direct use of molecular …

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

Q Yang, Q Wang, Z Yu - Chemical Society Reviews, 2015 - pubs.rsc.org
Transition metal-catalyzed substitution of alcohols by N-nucleophiles (or N-alkylation of
amines and related compounds with alcohols) avoids the use of alkylating agents by means …

Aerobic copper-catalyzed organic reactions

SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …

Development of a General Non‐Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia

X Cui, X Dai, Y Deng, F Shi - Chemistry–A European Journal, 2013 - Wiley Online Library
The N‐alkylation of amines or ammonia with alcohols is a valuable route for the synthesis of
N‐alkyl amines. However, as a potentially clean and economic choice for N‐alkyl amine …

[PDF][PDF] Iron/amino acid catalyzed direct N‐alkylation of amines with alcohols

Y Zhao, SW Foo, S Saito - Angewandte Chemie-International …, 2011 - thevespiary.org
Higher amines are widely used in both the bulk and fine chemical industries as fundamental
materials, additives, dyes, agrochemicals, etc.[1] Therefore, the development of a selective N …

Impregnated ruthenium on magnetite as a recyclable catalyst for the N-alkylation of amines, sulfonamides, sulfinamides, and nitroarenes using alcohols as …

R Cano, DJ Ramon, M Yus - The Journal of organic chemistry, 2011 - ACS Publications
Various impregnated metallic salts on magnetite have been prepared, including cobalt,
nickel, copper, ruthenium, and palladium salts, as well as a bimetallic palladium–copper …

Tunable Triazole‐Phosphine‐Copper Catalysts for the Synthesis of 2‐Aryl‐1H‐benzo[d]imidazoles from Benzyl Alcohols and Diamines by Acceptorless …

Z Xu, DS Wang, X Yu, Y Yang… - Advanced Synthesis & …, 2017 - Wiley Online Library
Triazole‐phosphine‐copper complexes (TAP− Cu) have been synthesized and applied as
tunable and efficient catalysts for the selective synthesis of fluoro‐substituted 2‐aryl‐1H …

Nickel‐catalyzed N‐alkylation of acylhydrazines and arylamines using alcohols and enantioselective examples

P Yang, C Zhang, Y Ma, C Zhang, A Li… - Angewandte Chemie …, 2017 - Wiley Online Library
A borrowing‐hydrogen reaction between amines and alcohols is an atom‐economic way to
prepare alkylamines, ideally with water as the sole byproduct. Herein, nickel catalysts are …

New Iridium Catalysts for the Selective Alkylation of Amines by Alcohols under Mild Conditions and for the Synthesis of Quinolines by Acceptor‐less Dehydrogenative …

S Ruch, T Irrgang, R Kempe - Chemistry–A European Journal, 2014 - Wiley Online Library
A novel family of iridium catalysts stabilised by P, N‐ligands have been introduced. The
ligands are based on imidazo [1, 5‐b] pyridazin‐7‐amines and can be synthesised with a …