Bridging Aromatic/Antiaromatic Units: Recent Advances in Aromaticity and Antiaromaticity in Main‐Group and Transition‐Metal Clusters from Bonding and Magnetic …
Synthetic exploration and theoretical characterization of metal clusters are actively
developing branches of modern inorganic chemistry. Advances in these areas constantly …
developing branches of modern inorganic chemistry. Advances in these areas constantly …
Cluster Chemistry with (Pseudo-)Tetrahedra Involving Group 13–15 (Semi-)Metal Atoms
F Pan, L Guggolz, S Dehnen - CCS Chemistry, 2022 - chinesechemsoc.org
Compounds containing (pseudo-) tetrahedral main group (semi-) metal units are
fundamentally important in three aspects. First, they provide new strategies for the …
fundamentally important in three aspects. First, they provide new strategies for the …
Supramolecular compounds assembled from the heteroleptic tetrahedral complex [{CpMo (CO) 2} 2 (μ, η 2-AsSb)] and metal salts
ME Moussa, PA Shelyganov, M Seidl… - Chemical …, 2024 - pubs.rsc.org
Supramolecular compounds assembled from the heteroleptic tetrahedral complex [{CpMo(CO)
2 } 2 (μ,η 2 -AsSb)] and metal salts - Chemical Communications (RSC Publishing) DOI:10.1039/D4CC01001A …
2 } 2 (μ,η 2 -AsSb)] and metal salts - Chemical Communications (RSC Publishing) DOI:10.1039/D4CC01001A …
Soft interactions with hard Lewis acids: generation of mono-and dicationic alkaline-earth metal arene-complexes by direct oxidation
M Schorpp, I Krossing - Chemical Science, 2020 - pubs.rsc.org
The synthesis of the first unsupported dicationic arene complexes of calcium and strontium
[(η6-HMB) AE (oDFB) 4] 2+ is reported (HMB= hexamethylbenzene; AE= alkaline earth …
[(η6-HMB) AE (oDFB) 4] 2+ is reported (HMB= hexamethylbenzene; AE= alkaline earth …
Building blocks for the chemistry of perfluorinated alkoxyaluminates [Al {OC (CF 3) 3} 4]−: simplified preparation and characterization of Li+–Cs+, Ag+, NH 4+, N 2 H 5 …
PJ Malinowski, T Jaroń, M Domańska, JM Slattery… - Dalton …, 2020 - pubs.rsc.org
Advanced weakly coordinating anions (WCAs) significantly facilitate synthesis of various
exotic chemical compounds and novel, potentially useful materials. One of such anions–[Al …
exotic chemical compounds and novel, potentially useful materials. One of such anions–[Al …
Synthesis of a hexachloro sulfate (IV) dianion enabled by polychloride chemistry
P Voßnacker, A Wüst, C Müller… - Angewandte Chemie …, 2022 - Wiley Online Library
The preparation and structural characterization of [NEt3Me] 2 [SCl6] is described, which is
the first example of a [SCl6] 2− dianion and of a halosulfate anion of the type [SxXy] z− in …
the first example of a [SCl6] 2− dianion and of a halosulfate anion of the type [SxXy] z− in …
Capture the missing: formation of (PbBi3)− and {[AuPb5Bi3]2}4− via atom exchange or reorganization of the pseudo‐tetrahedral Zintl anion (Pb2Bi2)2−
F Pan, L Guggolz, S Dehnen - Natural Sciences, 2022 - Wiley Online Library
Abstract (Pseudo‐) tetrahedral p‐block atom units have been attracting the interest of many
scientists, mainly regarding their use as elegant starting materials for compounds with larger …
scientists, mainly regarding their use as elegant starting materials for compounds with larger …
Cationic Group 13 and 14 Element Clusters
A Barthélemy, I Krossing - Inorganic Chemistry, 2024 - ACS Publications
Anionic and neutral clusters dominate the cluster chemistry of group 13 and 14 elements,
many of which have become classic textbook examples of main group element clusters …
many of which have become classic textbook examples of main group element clusters …
Formation of the elusive tetrahedral P3N molecule
C Zhang, C Zhu, AK Eckhardt, RI Kaiser - Science Advances, 2022 - science.org
The tetrahedral 1, 2, 3-triphospha-4-azatricyclo [1.1. 0.02, 4] butane (P3N) molecule—an
isovalent species of phosphorus (P4)—was prepared in low-temperature (5 K) phosphine …
isovalent species of phosphorus (P4)—was prepared in low-temperature (5 K) phosphine …
On the Synthesis and Structure of 'Naked'Ga (I) and In (I) Salts and the Surprising Stability of Simple Ga (I) and In (I) Salts in the Coordinating Solvents Ether and …
A Barthélemy, H Scherer, H Weller… - Chemistry–A European …, 2024 - Wiley Online Library
In this work, we present the solid‐state structures of solvent‐free Ga [pf] and In [pf] salts
([pf]−=[Al (ORF) 4]−; RF= C (CF3) 3), which are very rare examples of salts with truly …
([pf]−=[Al (ORF) 4]−; RF= C (CF3) 3), which are very rare examples of salts with truly …