Ring-opening polymerization (ROP) and catalytic rearrangement as a way to obtain siloxane mono-and telechelics, as well as well-organized branching centers …

KA Bezlepkina, SA Milenin, NG Vasilenko… - Polymers, 2022 - mdpi.com
PDMS telechelics are important both in industry and in academic research. They are used
both in the free state and as part of copolymers and cross-linked materials. At present, the …

New principles of polymer composite preparation. MQ copolymers as an active molecular filler for polydimethylsiloxane rubbers

IB Meshkov, AA Kalinina, VV Gorodov, AV Bakirov… - Polymers, 2021 - mdpi.com
Colorless transparent vulcanizates of silicone elastomers were prepared by mixing the
components in a common solvent followed by solvent removal. We studied the correlation …

[HTML][HTML] Factors Determining Unique Thermal Resistance and Surface Properties of Silicone-Containing Composites

M Zielecka, A Rabajczyk - Materials, 2024 - mdpi.com
This review discusses the key factors influencing the exceptional thermal resistance and
surface properties of silicone-containing composites. Silicone polymers, known for their …

Acid-Catalyzed Rearrangement of Azidopropyl-Siloxane Monomers for the Synthesis of Azidopropyl-Polydimethylsiloxane and Their Carboxylic Acid Derivatives

SA Milenin, FV Drozdov, KA Bezlepkina… - …, 2021 - ACS Publications
In this work, we were the first to show the possibility of synthesizing polydimethylsiloxanes
(PDMSs) with azidopropyl-functional groups at the silicon atom by the classical methods for …

Functional silsesquioxane polymers with branched perfluoroalkyl substituents: Synthesis and prospect applications

US Andropova, FV Drozdov, PD Shkinev… - European Polymer …, 2022 - Elsevier
Condensation of alkoxysilanes in the active medium, which means acetic or trifluoroacetic
acids, is a convenient and versatile method for preparing silsesquioxane copolymers with …

Amphiphilic molecular brushes with regular polydimethylsiloxane backbone and poly-2-isopropyl-2-oxazoline side chains. 1. Synthesis, characterization and …

S Rodchenko, A Amirova, S Milenin, A Ryzhkov… - European Polymer …, 2020 - Elsevier
The samples of molecular brushes with a polydimethylsiloxane backbone and side chains of
poly-2-isopropyl-2-oxazoline have been synthesized. Regular polydimethylsiloxane with …

Use of a hydrosilylation reaction for the preparation of structure-controlled boroxine-based polyborosiloxanes

EA Manokhina, RS Tukhvatshin, DA Khanin… - Reactive and Functional …, 2024 - Elsevier
The structure of organosilicon vinyl-containing boroxine was confirmed by 1 H nuclear
magnetic resonance (NMR) spectroscopy, infrared (IR) spectroscopy and matrix-assisted …

Synthesis of functional derivatives of stereoregular organocyclosilsesquioxanes by thiol-ene addition

Y Vysochinskaya, A Anisimov, F Krylov, M Buzin… - Journal of …, 2021 - Elsevier
The paper presents a facile and convenient thiol-ene addition method for the modification of
cis-tetravinylcyclotetrasiloxanes containing trimethylsiloxy or dimethyl (vinyl) siloxy units at …

Synthesis of 1, 1, 3, 3, 5, 5-Hexamethyl-7, 7-diorganocyclotetrasiloxanes and Its Copolymers

EV Talalaeva, AA Kalinina, EV Chernov… - Polymers, 2021 - mdpi.com
This paper reports a method for the synthesis of 1, 1, 3, 3, 5, 5-hexamethyl-7, 7-
diorganocyclotetrasiloxanes by the interaction of 1, 5-disodiumoxyhexamethylsiloxane with …

Organosilicon Comb-Shaped Surfactants for the Synthesis of Polymer Suspensions with a Narrow Particle Size Distribution

AA Ezhova, IA Gritskova, SA Gusev, SA Milenin… - … Science, Series B, 2021 - Springer
The polymerization of styrene in the presence of an organosilicon comb-shaped surfactant,
α, ω‑bis (trimethylsiloxy)-oligodimethylmethyl-(10-carboxydecyl) siloxane, is studied. The …