Importance of size and contact structure of gold nanoparticles for the genesis of unique catalytic processes

T Ishida, T Murayama, A Taketoshi, M Haruta - Chemical reviews, 2019 - ACS Publications
Since the discovery of catalysis by Au nanoparticles (NPs), unique catalytic features of Au
have appeared that are greatly different from those of Pd and Pt. In this Review, we aimed to …

Low-temperature heterogeneous oxidation catalysis and molecular oxygen activation

UJ Etim, P Bai, OM Gazit, Z Zhong - Catalysis Reviews, 2023 - Taylor & Francis
Many natural oxidations are relevant to the origin and running of life but usually proceeded
under mild conditions using molecular oxygen (O2) in the air as the sole oxidant and …

Highly Efficient Catalysis of Preferential Oxidation of CO in H2-Rich Stream by Gold Single-Atom Catalysts

B Qiao, J Liu, YG Wang, Q Lin, X Liu, A Wang, J Li… - ACS …, 2015 - ACS Publications
Preferential oxidation of CO (PROX) in H2-rich stream is critical to the production of clean H2
for the H2-based fuel cells, which provide clean and efficient energy conversion …

Boosting the catalysis of gold by O2 activation at Au-SiO2 interface

Y Zhang, J Zhang, B Zhang, R Si, B Han… - Nature …, 2020 - nature.com
Supported gold (Au) nanocatalysts have attracted extensive interests in the past decades
because of their unique catalytic properties for a number of key chemical reactions …

Controlling activity and selectivity using water in the Au-catalysed preferential oxidation of CO in H2

J Saavedra, T Whittaker, Z Chen, CJ Pursell… - Nature Chemistry, 2016 - nature.com
Industrial hydrogen production through methane steam reforming exceeds 50 million tons
annually and accounts for 2–5% of global energy consumption. The hydrogen product, even …

H2 Oxidation over Supported Au Nanoparticle Catalysts: Evidence for Heterolytic H2 Activation at the Metal–Support Interface

T Whittaker, KBS Kumar, C Peterson… - Journal of the …, 2018 - ACS Publications
Water adsorbed at the metal–support interface (MSI) plays an important role in multiple
reactions. Due to its importance in CO preferential oxidation (PrOx), we examined H2 …

CO Oxidation Kinetics over Au/TiO2 and Au/Al2O3 Catalysts: Evidence for a Common Water-Assisted Mechanism

J Saavedra, CJ Pursell… - Journal of the American …, 2018 - ACS Publications
The mechanism of CO oxidation over supported gold catalysts has long been debated, with
two prevailing mechanisms dominating the discussion: a water-assisted mechanism and a …

Recent advances in synergistic effect promoted catalysts for preferential oxidation of carbon monoxide

P Jing, X Gong, B Liu, J Zhang - Catalysis Science & Technology, 2020 - pubs.rsc.org
Preferential oxidation of CO (PROX) in a H2-rich stream is considered as a promising
strategy for abatement of trace amounts of CO to prevent poisoning of Pt anodes by H2 in …

Improved CO-PROX selectivity of CuO/CeO2 catalysts by decorating with lanthanum via surface Cuξ+ redox site

L Wang, Q Li, X Liu, C Li, Z Zhao, S Diao, D Cao… - Applied Surface …, 2024 - Elsevier
Hydrogen purification is essential to satisfy the various purity requirements for different
applications. Preferential oxidation of carbon monoxide (CO-PROX) is a promising strategy …

CO oxidation and COPrOx over preformed Au nanoparticles supported over nanoshaped CeO2

L Soler, A Casanovas, A Urrich, I Angurell… - Applied Catalysis B …, 2016 - Elsevier
Abstract Au/CeO 2 (0.25% wt. Au) catalysts were prepared by anchoring preformed Au
nanoparticles over ceria polycrystals, cubes and rods and tested in the oxidation of CO and …