MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Introducing Frustrated Lewis Pairs to Metal–Organic Framework for Selective Hydrogenation of N-Heterocycles

ZM Xu, Z Hu, Y Huang, SJ Bao, Z Niu… - Journal of the …, 2023 - ACS Publications
Hydrogenated nitrogen heterocyclic compounds play a critical role in the pharmaceutical,
polymer, and agrochemical industries. Recent studies on partial hydrogenation of nitrogen …

Pyrene-based metal organic frameworks: from synthesis to applications

FP Kinik, A Ortega-Guerrero, D Ongari… - Chemical Society …, 2021 - pubs.rsc.org
Pyrene is one of the most widely investigated aromatic hydrocarbons given to its unique
optical and electronic properties. Hence, pyrene-based ligands have been attractive for the …

Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions

A Iliescu, JJ Oppenheim, C Sun, M Dincǎ - Chemical Reviews, 2023 - ACS Publications
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …

Nickel catalyzed olefin oligomerization and dimerization

H Olivier-Bourbigou, PAR Breuil, L Magna… - Chemical …, 2020 - ACS Publications
Brought to life more than half a century ago and successfully applied for high-value
petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very …

Postsynthetic tuning of metal–organic frameworks for targeted applications

T Islamoglu, S Goswami, Z Li, AJ Howarth… - Accounts of chemical …, 2017 - ACS Publications
Conspectus Metal–organic frameworks (MOFs) are periodic, hybrid, atomically well-defined
porous materials that typically form by self-assembly and consist of inorganic nodes (metal …

Metal–organic frameworks with catalytic centers: From synthesis to catalytic application

YS Kang, Y Lu, K Chen, Y Zhao, P Wang… - Coordination chemistry …, 2019 - Elsevier
Abstract Metal-organic frameworks (MOFs), as a new stable class of hybrid materials
synthesized, regulated and decorated by rational incorporating organic bridging ligands and …

3D Covalent Organic Frameworks with 16-Connectivity for Photocatalytic C(sp3)–C(sp2) Cross-Coupling

M Lu, SB Zhang, RH Li, LZ Dong… - Journal of the …, 2024 - ACS Publications
The connectivity (valency) of building blocks for constructing 3D covalent organic
frameworks (COFs) has long been limited to 4, 6, 8, and 12. Developing a higher …