Metal complexes of porphyrinoids containing nonpyrrolic heterocycles

DW Thuita, C Brückner - Chemical Reviews, 2022 - ACS Publications
The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

Carbaporphyrinoid systems

TD Lash - Chemical reviews, 2017 - ACS Publications
Following immediately after the serendipitous discovery of N-confused porphyrins,
remarkably diverse carbaporphyrinoid systems have been synthesized and investigated. By …

Synthesis of aza-, oxa-, and thiaporphyrins and related compounds

Y Matano - Chemical Reviews, 2017 - ACS Publications
Chemical modification at the periphery with nitrogen or chalcogens is a highly promising
strategy to diversify the optical, electrochemical, magnetic, and coordination properties of the …

Modifications of porphyrins and hydroporphyrins for their solubilization in aqueous media

M Luciano, C Brückner - Molecules, 2017 - mdpi.com
The increasing popularity of porphyrins and hydroporphyrins for use in a variety of
biomedical (photodynamic therapy, fluorescence tagging and imaging, photoacoustic …

The Breaking and Mending of meso-Tetraarylporphyrins: Transmuting the Pyrrolic Building Blocks

C Bruckner - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Naturally occurring porphyrins and hydroporphyrins vary with respect to their
ring substituents and oxidation states, but their tetrapyrrolic frameworks remain fully …

Direct Oxidations of meso-Tetrakis(pentafluorophenyl)porphyrin: Porphotrilactones and Entry into a Nonbiological Porphyrin Degradation Pathway

N Hewage, D Damunupola, M Zeller… - The Journal of Organic …, 2024 - ACS Publications
The direct oxidations of meso-tetrakis (pentafluorophenyl) porphyrin using
cetyltrimethylammonium permanganate (CTAP), RuCl3/Oxone/base or Ag+/oxalic acid each …

Porphyrin macrocycle modification: Pyrrole ring-contracted or-expanded porphyrinoids

LD Costa, JIT Costa, AC Tomé - Molecules, 2016 - mdpi.com
In recent years, several synthetic strategies aiming at the peripheral functionalization of
porphyrins were developed. Particularly interesting are those involving the modification of β …

Bacterio- and Isobacteriodilactones by Stepwise or Direct Oxidations of meso-Tetrakis(pentafluorophenyl)porphyrin

N Hewage, P Daddario, KSF Lau… - The Journal of …, 2018 - ACS Publications
Porpholactones are porphyrinoids in which one or more β, β′-bonds of the parent
chromophore were replaced by lactone moieties. Accessible to varying degrees by direct …

Telluracarbaporphyrins and a related palladium (II) complex: evidence for hypervalent interactions

TD Lash, DI AbuSalim, GM Ferrence - Inorganic Chemistry, 2021 - ACS Publications
The reaction of a carbatripyrrin with a tellurophene dicarbinol in the presence of BF3· Et2O,
followed by oxidation with DDQ, afforded the first example of a telluracarbaporphyrin …

Bacteriochlorins with a twist: Discovery of a unique mechanism to red-shift the optical spectra of bacteriochlorins

MJ Guberman-Pfeffer, JA Greco… - Journal of the …, 2017 - ACS Publications
Owing to their intense near infrared absorption and emission properties, to the ability to
photogenerate singlet oxygen, or to act as photoacoustic imaging agents within the optical …