The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
The direct synthesis of hydrogen peroxide (H2+ O2→ H2O2) may enable low-cost H2O2 production and reduce environmental impacts of chemical oxidations. Here, we synthesize a …
NM Wilson, DW Flaherty - Journal of the American Chemical …, 2016 - ACS Publications
Direct synthesis (H2+ O2→ H2O2) is a promising reaction for producing H2O2, which can replace chlorinated oxidants in industrial processes. The mechanism of this reaction and the …
Catalytic reactions that utilize H2O2 as a terminal oxidant possess high selectivities for industrially relevant oxidations that rival Cl2 mediated chemistry and reactions with organic …
We examine relationships between H2O2 and H2O formation on metal nanoparticles by the electrochemical oxygen reduction reaction (ORR) and the thermochemical direct synthesis …
Abstract Direct synthesis (H 2+ O 2→ H 2 O 2) could produce H 2 O 2 (an environmentally benign oxidant) more cost-effectively and sustainably than anthraquinone oxidation …
Many natural oxidations are relevant to the origin and running of life but usually proceeded under mild conditions using molecular oxygen (O2) in the air as the sole oxidant and …
VR Naina, S Wang, DI Sharapa, M Zimmermann… - ACS …, 2021 - ACS Publications
Hydrogen peroxide production by direct synthesis (H2+ O2→ H2O2) is a promising alternative to the commercialized indirect process involving sequential hydrogenation and …
The introduction of small quantities of tertiary base metals into supported AuPd nanoparticles results in improved catalytic performance towards the direct synthesis of …