Elementary photocatalytic chemistry on TiO 2 surfaces

Q Guo, C Zhou, Z Ma, Z Ren, H Fan… - Chemical Society Reviews, 2016 - pubs.rsc.org
Photocatalytic hydrogen production and pollutant degradation provided both great
opportunities and challenges in the field of sustainable energy and environmental science …

Structure of Clean and Adsorbate-Covered Single-Crystal Rutile TiO2 Surfaces

CL Pang, R Lindsay, G Thornton - Chemical reviews, 2013 - ACS Publications
TiO 2 is exploited in a number of applications, including solar power, catalysis, gas sensing,
and corrosion protection, where surface properties are central to operation. This commercial …

Molecular-Level Insights into Photocatalysis from Scanning Probe Microscopy Studies on TiO2(110)

MA Henderson, I Lyubinetsky - Chemical Reviews, 2013 - ACS Publications
The field of heterogeneous photocatalysis has grown considerably in the decades since
Fujishima and Honda's ground-breaking publications on photoelectrochemistry on TiO2. 1 …

Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters

S Bonanni, K Aït-Mansour, W Harbich… - Journal of the American …, 2012 - ACS Publications
The catalytic activity of deposited Pt7 clusters has been studied as a function of the reduction
state of the TiO2 (110)-(1× 1) support for the CO oxidation reaction. While a slightly reduced …

Site requirements for the adsorption and reaction of oxygenates on metal oxide surfaces

JM Vohs - Chemical reviews, 2013 - ACS Publications
The diversity of the structure and composition of metal oxides allow these materials to have
a wide range of surface reactivities, and they are used extensively as catalysts for reactions …

Review of functional titanium oxides. II: Hydrogen-modified TiO2

N Rahimi, R Pax, EMA Gray - Progress in Solid State Chemistry, 2019 - Elsevier
Band gap engineering of TiO 2 has attracted many researchers looking to extend its
applicability as a functional material. Although TiO 2 has been commercialised in …

On surface chemical reactions of free-base and titanyl porphyrins with r-TiO 2 (110): a unified picture

L Schio, D Forrer, M Casarin, A Goldoni… - Physical Chemistry …, 2022 - pubs.rsc.org
In this Perspective we present a comprehensive study of the multiple reaction products of
metal-free porphyrins (2H-Ps) in contact with the rutile TiO2 (110) surface. In the absence of …

Molecular chemistry to the fore: New insights into the fascinating world of photoactive colloidal semiconductor nanocrystals

J Vela - The Journal of Physical Chemistry Letters, 2013 - ACS Publications
Colloidal semiconductor nanocrystals possess unique properties that are unmatched by
other chromophores such as organic dyes or transition-metal complexes. These versatile …

Low-temperature adsorption and diffusion of methanol in ZIF-8 nanoparticle films

AM Mosier, HLW Larson, ER Webster, M Ivos, F Tian… - Langmuir, 2016 - ACS Publications
The adsorption of methanol by a zeolitic imidazolate framework-8 (ZIF-8) nanoparticle thin
film was studied in situ using temperature-programmed desorption and X-ray photoelectron …

Digging Ti interstitials at the r-TiO2 (1 1 0) surface: Mechanism of porphyrin Ti sequestration by iminic N nucleophilic attack

MK Kremer, D Forrer, C Rogero, L Floreano… - Applied Surface …, 2021 - Elsevier
Ti interstitials are key actors in the reduction/re-oxidation processes of TiO 2. The charge
redistribution originated by these point defects is acknowledged to trigger the dissociation of …