Flash vacuum pyrolysis of azides, triazoles, and tetrazoles

C Wentrup - Chemical Reviews, 2017 - ACS Publications
Flash vacuum pyrolysis (FVP) of azides is an extremely valuable method of generating
nitrenes and studying their thermal rearrangements. The nitrenes can in many cases be …

Visible‐Light‐Driven Selective Oxidative Coupling of Amines to Imines by Bismuth‐Rich Bismuth Oxybromide in Water

W Zhao, C Yang, X Zhang, Y Deng, C Han… - …, 2020 - Wiley Online Library
Photocatalytic selective oxidative coupling of amines is a promising method for imine
synthesis. Bismuth‐rich bismuth oxybromide photocatalysts have been found to exhibit …

Continuous Flow-Facilitated CB2 Agonist Synthesis, Part 1: Azidation and [3+ 2] Cycloaddition

P Sagmeister, M Prieschl, D Kaldre… - … Process Research & …, 2023 - ACS Publications
We report the use of continuous flow processing to enable the first two steps of a new route
toward a cannabinoid receptor type 2 agonist, RG7774. First, an alkyl azide is formed using …

Synthesis and use of a hyper-connecting cross-linking agent in the hole-transporting layer of perovskite solar cells

BL Watson, N Rolston, KA Bush, L Taleghani… - Journal of Materials …, 2017 - pubs.rsc.org
Solution-processed organic semiconducting materials feature prominently in modern
optoelectronic devices, especially where low-cost and flexibility are specific goals, such as …

Thermal cross linking of novel azide modified polymers of intrinsic microporosity—effect of distribution and the gas separation performance

S Neumann, G Bengtson, D Meis, V Filiz - Polymers, 2019 - mdpi.com
The synthesis of polymers of intrinsic microporosity (PIM) modified with azide groups, the
cross linkage by nitrene reaction and their performance as gas separation membranes are …

Pristine graphene covalent functionalization with aromatic aziridines and their application in the sensing of volatile amines–an ab initio investigation

S Baachaoui, S Aldulaijan, F Raouafi, R Besbes… - RSC …, 2021 - pubs.rsc.org
Food quality is of paramount importance for public health safety. For instance, fish freshness
can be assessed by sensing the volatile short chain alkylamines produced by spoiled fish …

Improved synthesis route and performance of azide modified polymers of intrinsic microporosity after thermal self-crosslinking

H Ling, J Jin - Polymer, 2021 - Elsevier
A new azide modified biscatechol monomer was first obtained and characterized by single-
crystal XRD, but its polymerization only afforded a low molecular weight azide-containing …

Comment on “The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzenemethanimine Formation”

C Wentrup - The Journal of Physical Chemistry A, 2015 - ACS Publications
J. Phys. Chem. A 2015, 119 (18), 4118− 4126. DOI: 10. 1021/acs. jpca. 5b02453 J. Phys.
Chem. A 2015, 119. DOI: 10.1021/acs. jpca. 5b04334 A recently published paper by Pinto et …

Spectroscopic and Structural Characterization of Reactive Metal Nitrenoids

GP Van Trieste III - 2022 - search.proquest.com
C–H bonds are the most ubiquitous functional groups found in nature. While C–H bonds are
abundant, they are oxidatively robust due to the lack of polarity about the C–H bond and …

Reply to “Comment on 'The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzemethanimine Formation'”

RM Pinto, M Guerra, ML Costa… - The Journal of Physical …, 2015 - ACS Publications
J. Phys. Chem. A 2015, 119 (18) 4118− 4126. DOI: 10. 1021/acs. jpca. 5b02453 J. Phys.
Chem. A 2015, 119. DOI: 10.1021/acs. jpca. 5b04198 In a comment 1 to our recent work, 2 …