The past decade has witnessed tremendous developments in transition‐metal‐catalyzed C−
H bond activation and subsequent carbene migratory insertion reactions, thus assisting in …

Diazo compounds being used as a precursor of carbenes in synthetic chemistry by reacting
them in different manners like photochemically, thermally or with metal catalysts. Further, the …

Enantioselective 7-exo-trig cyclocarbopalladation-initiated carbonylation cascade reactions,
leading to seven-membered dibenzo [b, d] azepin-6-ones containing a thermodynamically …

An efficient and regioselective synthesis of fused polycyclic furo [3, 4-c] indolo [2, 1-a]
isoquinolines through Rh (III)-catalyzed cascade C–H activation/annulation/lactonization of …

Chemodivergent synthesis of indeno [1, 2-b] indoles and isoindolo [2, 1-a] indoles from the
same starting materials involving radical cross-dehydrogenative couplings have been …

The rhodium-catalyzed mono-ortho C–H activation/carbenoid insertion/aldol-type cyclization
of 3-aldehyde-2-phenyl-1H-indoles with diazo compounds has been developed. This …

We report herein the facile synthesis of indole-fused six-, seven-, or eight-membered N, O-
heterocycles through rhodium-catalyzed C–H acetoxylation/hydrolysis/annulation. The …

A novel and mild Rh (III)-catalyzed C–H activation/intramolecular condensation of 1-aryl-1H-
pyrazol-5-amines with cyclic 2-diazo-1, 3-diketones was developed, giving access to various …

Diversity-oriented synthesis strategy for the efficient assembly of indole-fused polycyclic
scaffolds via rhodium-catalyzed NH-indole-directed C–H coupling with propargylic alcohol …

Using enynones and diazo carbonyl compounds as identical starting materials, methods for
chemoselective and regioselective constructs of diazo-functionalized 2-methylene-2, 3 …