Bimetallic Perthiocarbonate Complexes of Cobalt: Synthesis, Structure and Bonding

AN Pradhan, S Mishra, U Kaur, BK Rout, JF Halet… - Molecules, 2024 - mdpi.com
The syntheses and structural elucidation of bimetallic thiolate complexes of early and late
transition metals are described. Thermolysis of the bimetallic hydridoborate species [{Cp …

Thiolate-Bridged Heterodinuclear Manganese–Cobalt Complexes with Bridging Hydride Ligands

K Pathak, S Mishra, S Bairagi, B Rajeshwaree… - …, 2022 - ACS Publications
Synthesis and structural elucidation of a series of thiolate-bridged heterobimetallic MnCo
complexes are described. Irradiation of [Mn2 (CO) 10] in the presence of Li [BH3SPh] …

Nature of Metal–Metal Bond in Group‐V Dinuclear Metallaborane Compounds: Open‐Shell–Open‐Shell Vs Closed‐Shell–Closed‐Shell Interaction

HS Karnamkkott, KC Mondal - European Journal of Inorganic …, 2024 - Wiley Online Library
The investigation of metal–metal bonding is interesting due to the captivating structural
features, unique chemical reactivity and physical properties of this class of complexes. The …

SAMAROCENECHALCOGENIDES (Q= S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q 2–SYNTHON IN REACTIONS WITH CS2

BY Savkov, TS Sukhikh, SN Konchenko - Journal of Structural Chemistry, 2022 - Springer
Reactions of decamethylsamarocene monochalcogenides (Cp*= η5-C5 (CH3) 5; Q= S (1),
Se (2), Te (3)) with carbon disulfide are studied. It is established that these reactions lead to …

Syntheses, Structures, and Electronic Properties of Mono‐and Bimetallic Thiolato Complexes Containing Unusual Coordination Modes of Thiolato Ligands

S Bairagi, AN Pradhan, M Cordier… - European Journal of …, 2023 - Wiley Online Library
Synthesis, bonding and chemistry of mono‐and bimetallic complexes supported by
chelating thiolato ligands have been established. Treatment of [Cp* VCl2] 3 (1) with [LiBH4⋅ …

САМАРОЦЕНХАЛЬКОГЕНИДЫ [{CP* 2 SM (THF)} 2 (μ-Q)](Q= S, SE, TE)-СИНТЕТИЧЕСКИЕ ЭКВИВАЛЕНТЫ СИНТОНА Q 2-В РЕАКЦИЯХ С CS 2

БЮ САВКОВ, ТС СУХИХ, СН КОНЧЕНКО - ЖУРНАЛ СТРУКТУРНОЙ …, 2022 - elibrary.ru
Изучены реакции монохалькогенидов декаметилсамароцена [{Cp* 2 Sm (THF)} 2 (μ-
Q)](Cp*= η 5-C 5 (CH 3) 5; Q= S (1), Se (2), Te (3)) с сероуглеродом. Установлено, что эти …