Ruthenium complexes of N/O/S based multidentate ligands: Structural diversities and catalysis perspectives

S Yadav, P Vijayan, R Gupta - Journal of Organometallic Chemistry, 2021 - Elsevier
Recent time has witnessed remarkable advances in the coordination and the organometallic
chemistry of ruthenium. Such a growth is primarily due to the propensity of ruthenium …

Targeting Pathogenic Formate-Dependent Bacteria with a Bioinspired Metallo–Nitroreductase Complex

C Weng, H Yang, BS Loh, MW Wong… - Journal of the American …, 2023 - ACS Publications
Nitroreductases (NTRs) constitute an important class of oxidoreductase enzymes that have
evolved to metabolize nitro-containing compounds. Their unique characteristics have …

Cell death mechanism of organometallic ruthenium (II) and iridium (III) arene complexes on HepG2 and Vero cells

SB Kavukcu, HK Ensarioğlu, H Karabıyık… - ACS …, 2023 - ACS Publications
Due to side effects and toxicity associated with platinum-derived metal-based drugs,
extensive research has been conducted on ruthenium (Ru) complexes. We aim to …

Supramolecular catalysis: the role of H-bonding interactions in substrate orientation and activation

S Pachisia, R Gupta - Dalton Transactions, 2021 - pubs.rsc.org
Hydrogen bonding plays significant roles in various biological processes during substrate
orientation and binding and therefore assists in assorted organic transformations. However …

Hydration of Nitriles Catalyzed by Ruthenium Complexes: Role of Dihydrogen Bonding Interactions in Promoting Base-Free Catalysis

S Yadav, R Gupta - Inorganic Chemistry, 2022 - ACS Publications
Ru (II) complexes of amide-phosphine-based tridentate ligands additionally containing
pyridine, isoquinoline, and quinoline rings have been synthesized, and their catalytic utility …

Ethanol as hydrogen donor: An efficient transfer hydrogenation of aldehydes, ketones, and nitroarenes with H-bonded Ru (II)-N-heterocyclic iminium complex

S Revathi, T Ghatak - Journal of Catalysis, 2024 - Elsevier
Isopropanol and formic acid are predominantly utilized as hydrogen sources in catalytic
transfer hydrogenation reactions. However, the utilization of primary alcohols in such …

Ruthenium (III) acyl thiourea complex: A catalyst for transfer hydrogenation of nitroarenes

ME Uysal, U Solmaz, H Arslan - Polyhedron, 2024 - Elsevier
The complex of ruthenium (III)([RuCl 2 (PPh 3) 2 BTU], 1) was prepared by reacting the
acylthiourea ligand with a ruthenium salt ([RuCl 2 (PPh 3) 3]), and has been thoroughly …

Cascade Performance of Nitroarenes with Alcohols Boosted by a Hollow Flying Saucer-Shaped Ni–Al2O3 Catalyst via a MOF-Templated Strategy Induced by the …

W Li, J Shi, D He, H Chen - Inorganic Chemistry, 2023 - ACS Publications
Catalysts with an open hollow structure can enhance the mass transfer capability of the
catalyst during the reaction process, thereby further improving the catalytic performance. In …

One-dimensional rare-earth La-MOFs coordinated with hexamethylenetetramine-Co MOFs derived highly efficient catalyst for cascade reaction of nitroarenes with …

D Deng, W Song, W Li, Q Li, X Wang - Journal of Rare Earths, 2024 - Elsevier
A composite metal-organic frameworks (MOFs) structure, designated as Co-hmta@ La-
salen, was synthesized through coordination interactions between a one-dimensional …

Molecular assemblies offering hydrogen-bonding cavities: influence of macrocyclic cavity and hydrogen bonding on dye adsorption

S Pachisia, R Gupta, R Gupta - Inorganic Chemistry, 2022 - ACS Publications
This work presents a set of Hg macrocycles of amide-phosphine-based ligands offering H-
bonding cavities of different dimensions. Such macrocycles are shown to selectively adsorb …