Organic and molecular magnets

SJ Blundell, FL Pratt - Journal of Physics: Condensed Matter, 2004 - iopscience.iop.org
Historically most materials in magnetic applications are based on inorganic materials.
Recently, however, organic and molecular materials have begun to show increasing …

Recent progress in the development of organomagnetic materials based on neutral nitroxide radicals and charge transfer complexes derived from nitroxide radicals

H Anzai - Journal of Materials Chemistry, 1997 - pubs.rsc.org
Nitroxide radicals play a central role in the recent development of organomagnetic materials
or molecular-based magnetic materials. This feature article considers the recent progress in …

Conducting organic radical cation salts with organic and organometallic anions

U Geiser, JA Schlueter - Chemical reviews, 2004 - ACS Publications
Since the discovery of high electrical conductivity in an organic complex in 1954, 1 the field
of molecular conductors has stimulated a great deal of research. A large number of electron …

Organic Radicals Exhibiting Intermolecular Ferromagnetic Interactions with High Probability: 4-Arylmethyleneamino-2, 2, 6, 6-tetramethylpiperidin-1-yloxyls and …

K Togashi, R Imachi, K Tomioka, H Tsuboi… - Bulletin of the Chemical …, 1996 - jlc.jst.go.jp
A series of 4-arylmethyleneamino-2, 2, 6, 6-tetramethylpiperidin-1-yloxyls (4-
arylmethyleneamino-TEMPO) and related compounds were synthesized, and their magnetic …

Theoretical studies of spin arrangement of adsorbed organic radicals in metal-organic nanoporous cavity

T Kawakami, S Takamizawa, Y Kitagawa, T Maruta… - Polyhedron, 2001 - Elsevier
The adsorption properties in nanoporous crystals of a metal-organic framework were studied
theoretically. The Zn3 (BDC) 3· 6CH3OH (BDC= 1, 4-benzenedicarboxylate) crystal was …

Remarkably strong intermolecular antiferromagnetic couplings in the crystal of biphenyl-3, 5-diyl bis (tert-butyl nitroxide)

G Kurokawa, T Ishida, T Nogami - Chemical physics letters, 2004 - Elsevier
Magnetic susceptibility measurements of biphenyl-3, 5-diyl bis (t-butyl nitroxide) diradical
showed practically diamagnetic behavior over a temperature range 1.8–300 K. The strong …

Molecular S = 2 High-Spin, S = 0 Low-Spin and S = 0 ⇄ 2 Spin-Transition/-Crossover Nickel(II)-Bis(nitroxide) Coordination Compounds

T Ishida, S Ito, Y Homma, Y Kyoden - Inorganics, 2021 - mdpi.com
Heterospin systems have a great advantage in frontier orbital engineering since they utilize
a wide diversity of paramagnetic chromophores and almost infinite combinations and mutual …

Solid-State High-Resolution 1H and 2D NMR Study of the Electron Spin Density Distribution of the Hydrogen-Bonded Organic Ferromagnetic Compound 4 …

G Maruta, S Takeda, R Imachi, T Ishida… - Journal of the …, 1999 - ACS Publications
The electron spin density distribution at hydrogen atoms of 4-hydroxyimino-2, 2, 6, 6-
tetramethylpiperidin-1-yloxyl (4-hydroxyimino-TEMPO), which has recently been shown to …

Super–superexchange coupling through a hydrogen bond in a linear copper (II) complex,[Cu (LH)(L)]· BF4· 2H2O (LH= N-tert-butyl-N-2-pyridylhydroxylamine)

A Okazawa, T Ishida - Chemical Physics Letters, 2009 - Elsevier
Crystal structure analysis of the title compound revealed the presence of a hydrogen bond in
an intermolecular LH⋯ L contact with the O⋯ O distance of 2.4252 (16) Å to form a one …

Structure and properties of novel M (dmit) 2 salts with the Me3N+-TEMPO cation radical (Me3N+-TEMPO= N, N, N-trimethyl (1-oxyl-2, 2, 6, 6-tetramethylpiperidin-4-yl) …

S Aonuma, H Casellas, C Faulmann… - Journal of Materials …, 2001 - pubs.rsc.org
Salts of the Me3N+-TEMPO cation radical (Me3N+-TEMPO= N, N, N-trimethyl (1-oxyl-2, 2, 6,
6-tetramethylpiperidin-4-yl) ammonium) with I− and PF6− are prepared. Their crystal …