RB Bernstein, DR Herschbach… - Journal of Physical …, 1987 - ACS Publications
The first workshop on an emerging subfield of chemical dynamics, dubbed dynamical stereochemistry, was held in Jerusalem, Israel in November, 1986. Outlined hereis the …
The transition state, which gates and modulates reactive flux, serves as the central concept in our understanding of activated reactions. The barrier height of the transition state can be …
AJ McCaffery, ZT Alwahabi, MA Osborne… - The Journal of chemical …, 1993 - pubs.aip.org
We have re‐examined critical experiments on collision induced rotational transfer (RT) and conclude that the probability of RT is controlled by the factors that control the probability of …
The steric requirements of activatedatom exchange reactions are examined in light of the detailed information becoming available from experiments and simulations. The results are …
AJ McCaffery - Physical Chemistry Chemical Physics, 2004 - pubs.rsc.org
The highly resolved experiments of modern collision and reaction dynamics indicate that momentum change provides the principal motive force for change at the single molecule …
M Baer, I Last, HJ Loesch - The Journal of chemical physics, 1994 - pubs.aip.org
In this work is presented a detailed quantum mechanical study of the Li+ HF (v= 0, j)→ LiF (v′, j′)+ H reaction in the low energy region 0.001≤ E tr≤ 0.15 eV. The theoretical …
The reaction 0 (3P)+ HBr—0H (X2I1)+ Br has been investigated experimentally. Two distinct approaches were pursued, differing primarily in the method of 0 (3P) atom production. The …
F Wang, K Liu - The Journal of Chemical Physics, 2016 - pubs.aip.org
Differential steric effects in Cl reactions with aligned CHD3(v1 = 1) by the R(0) and Q(1) transitions. I. Attacking the excited C–H bond | The Journal of Chemical Physics | AIP Publishing …
GW Johnston, H Kornweitz, I Schechter… - The Journal of …, 1991 - pubs.aip.org
The dynamical stereochemistry of the reaction of hot F atoms with HD is discussed with reference to the measured branching ratio using both exact and model classical trajectory …