Orientation and alignment in reactive beam collisions: recent progress

HJ Loesch - Annual Review of Physical Chemistry, 1995 - annualreviews.org
The concept of directional axis distributions and orientation-dependent reaction cross
sections is used to describe the effect of the mutual orientation of reagents on the outcome of …

Dynamical aspects of stereochemistry

RB Bernstein, DR Herschbach… - Journal of Physical …, 1987 - ACS Publications
The first workshop on an emerging subfield of chemical dynamics, dubbed dynamical
stereochemistry, was held in Jerusalem, Israel in November, 1986. Outlined hereis the …

Direct mapping of the angle-dependent barrier to reaction for Cl + CHD3 using polarized scattering data

H Pan, F Wang, G Czakó, K Liu - Nature chemistry, 2017 - nature.com
The transition state, which gates and modulates reactive flux, serves as the central concept
in our understanding of activated reactions. The barrier height of the transition state can be …

Rotational transfer, an angular momentum model

AJ McCaffery, ZT Alwahabi, MA Osborne… - The Journal of chemical …, 1993 - pubs.aip.org
We have re‐examined critical experiments on collision induced rotational transfer (RT) and
conclude that the probability of RT is controlled by the factors that control the probability of …

The chemical shape of molecules: an introduction to dynamic stereochemistry

RD Levine - Journal of Physical Chemistry, 1990 - ACS Publications
The steric requirements of activatedatom exchange reactions are examined in light of the
detailed information becoming available from experiments and simulations. The results are …

A new approach to molecular collision dynamics

AJ McCaffery - Physical Chemistry Chemical Physics, 2004 - pubs.rsc.org
The highly resolved experiments of modern collision and reaction dynamics indicate that
momentum change provides the principal motive force for change at the single molecule …

Three‐dimensional quantum mechanical study of the Li+ HF→ LiF+ H process: Calculation of integral and differential cross sections

M Baer, I Last, HJ Loesch - The Journal of chemical physics, 1994 - pubs.aip.org
In this work is presented a detailed quantum mechanical study of the Li+ HF (v= 0, j)→ LiF
(v′, j′)+ H reaction in the low energy region 0.001≤ E tr≤ 0.15 eV. The theoretical …

Dynamics of the reaction atomic oxygen (3P)+ hydrogen bromide: experimental investigation and theoretical modeling

KG McKendrick, DJ Rakestraw, RN Zare… - The Journal of …, 1988 - ACS Publications
The reaction 0 (3P)+ HBr—0H (X2I1)+ Br has been investigated experimentally. Two distinct
approaches were pursued, differing primarily in the method of 0 (3P) atom production. The …

Differential steric effects in Cl reactions with aligned CHD3 (v1= 1) by the R (0) and Q (1) transitions. I. Attacking the excited C–H bond

F Wang, K Liu - The Journal of Chemical Physics, 2016 - pubs.aip.org
Differential steric effects in Cl reactions with aligned CHD3(v1 = 1) by the R(0) and Q(1)
transitions. I. Attacking the excited C–H bond | The Journal of Chemical Physics | AIP Publishing …

The branching ratio in the F+ HD reaction: An experimental and computational study

GW Johnston, H Kornweitz, I Schechter… - The Journal of …, 1991 - pubs.aip.org
The dynamical stereochemistry of the reaction of hot F atoms with HD is discussed with
reference to the measured branching ratio using both exact and model classical trajectory …