The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Azines, such as pyridines, quinolines, pyrimidines, and pyridazines, are widespread
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …

Photocycloaddition is a powerful reaction to enable the conversion of alkenes into high-
value synthetic materials that are normally difficult to obtain under thermal conditions …

Controlling the enantioselectivity of hydrogen atom transfer (HAT) reactions has been a long-
standing synthetic challenge. While recent advances on photoenzymatic catalysis have …

Replacing planar aromatic rings in drug molecules with C (sp 3)-rich isosteric mimetics, such
as bicyclo [n. 1.1] alkanes, can significantly alter their physicochemical and pharmacokinetic …

Exploiting β-scission in aminophosphoranyl radicals for radical-mediated transformations
has been a longstanding challenge. In this study, we investigated the untapped potential of …

Herein, we disclose a facile and versatile trifluoromethylimination of alkene with a rationally
designed N-(diphenylmethylene)-1, 1, 1-trifluoromethanesulfonamide as a bench-stable and …

A new class of iminosulfonylation reagents were developed and extensively used in the 1, 2-
iminosulfonylation of various olefins. Olefins containing bioactive molecules, such as …

Abstract Efficient methods for synthesizing 1, 2‐aryl (alkenyl) heteroatomic cores,
encompassing heteroatoms such as nitrogen, oxygen, sulfur, and halogens, are of …

A unified strategy for the deoxygenative or desulfurative pyridylation of various alcohols and
thiols has been developed through a single‐electron transfer (SET) process of frustrated …