Conspectus Enantiopure atropisomers have become increasingly important in asymmetric
synthesis and catalysis, pharmaceutical science, and material science since the discovery of …

With the rapid development of asymmetric catalysis, the demand for the enantioselective
synthesis of complex and diverse molecules with different chiral elements is increasing …

Silicon-stereogenic chiral organosilanes have found increasing applications in synthetic
chemistry, medicinal chemistry, and materials science. In this context, various asymmetric …

A rhodium-catalyzed enantioselective construction of triorgano-substituted silicon-
stereogenic siloxanes and alkoxysilanes is developed. This process undergoes a direct …

Conspectus The development of highly effective chiral ligands is a key topic in enhancing
the catalytic activity and selectivity in metal-catalyzed asymmetric synthesis. Traditionally …

Silaspiranes have attracted particular attention due to their chiral spiro‐silicon center, which
serves as an ideal carbon isostere and can endow spiro‐analogs with distinct properties …

Despite a growing focus on the construction of highly enantioenriched silicon-stereogenic
organosilicon compounds, the enantioselective synthesis of silicon-stereogenic silanols …

Enantiopure Si-stereogenic organosilanes are highly valued in the fields of organic
synthesis, development of advanced materials, and drug discovery. However, they are not …

In recent years, transition-metal-catalyzed enantioselective C–H bond functionalization has
emerged as a powerful and attractive synthetic approach to access silicon-stereogenic …

The catalytic asymmetric synthesis of silicon-stereogenic organosilicon compounds has
been a long-standing challenging task and was recently accomplished through a handful of …