Electronic structure of the mixed valence system

P Novák, F Boucher, P Gressier, P Blaha, K Schwarz - Physical Review B, 2001 - APS
Electronic structure of the system Y 2− x M x BaNiO 5 (M= C a, S r) was calculated for x= 0,
0.2, and 0.5 using the full-potential linearized augmented-plane-wave method. To describe …

Displacive-type ferroelectricity from magnetic correlations within spin-chain

T Basu, VVR Kishore, S Gohil, K Singh, N Mohapatra… - Scientific Reports, 2014 - nature.com
Observation of ferroelectricity among non-d0 systems, which was believed for a long time an
unrealistic concept, led to various proposals for the mechanisms to explain the same (ie …

Size effect on magnetism and large magnetocaloric effect of Haldane chain antiferromagnet Er2BaNiO5

MY Ruan, ZL Guo, QC Luo, L Wang, XL Wei… - Journal of Alloys and …, 2023 - Elsevier
We investigated the size effect on magnetocaloric effect (MCE) of Haldane spin-chain
antiferromagnet Er 2 BaNiO 5. The bulk sample was prepared by solid state route and the …

Magnetoelectric coupling in the Haldane spin-chain system DyBaNiO

K Singh, T Basu, S Chowki, N Mahapotra, KK Iyer… - Physical Review B …, 2013 - APS
We report the results of various measurements, namely magnetization, complex dielectric
permittivity, and electric polarization (P), on Dy 2 BaNiO 5 as a function of temperature (T) …

Evolution of electronic structure with dimensionality in divalent nickelates

K Maiti, P Mahadevan, DD Sarma - Physical Review B, 1999 - APS
We investigate the evolution of electronic structure with dimensionality (d) of Ni-O-Ni
connectivity in divalent nickelates, NiO (3− d), La 2 NiO 4, Pr 2 NiO 4 (2− d), Y 2 BaNiO 5 (1 …

Nickel supermixed valence in stoichiometric BaNi0. 83O2. 5

JA Campá, E Gutierrez-Puebla, MA Monge… - Journal of Solid State …, 1994 - Elsevier
Single crystals of BaNi 0.83 O 2.5 were grown from mixtures of BaCO 3 and NiO using KOH
as a flux. The composition and the crystal structure have been established from X-ray single …

Extraordinarily large intrinsic magnetodielectric coupling of the Tb member within the Haldane spin-chain family

SK Upadhyay, PL Paulose, EV Sampathkumaran - Physical Review B, 2017 - APS
The Haldane spin-chain compound Tb 2 BaNiO 5 has been known to order
antiferromagnetically below (TN=) 63 K. The present magnetic studies on the polycrystals …

Neutron diffraction study of the magnetic ordering in the series R 2 BaNiO 5 (R = Rare Earth)

E Garcia-Matres, JL Martinez… - The European Physical …, 2001 - Springer
A neutron diffraction study, as a function of temperature, of the title compounds is presented.
The whole family (space group Immm, a≈ 3.8 Å, b≈ 5.8 Å, c≈ 11.3 Å) is structurally …

Impurities in s=1 Heisenberg antiferromagnets

ES So, I Affleck - Physical Review B, 1995 - APS
The s= 1 Heisenberg antiferromagnet is studied in the presence of two kinds of local
impurities. First, a perturbed antiferromagnetic bond with J'≠ J at the center of an even …

Magnetic susceptibility and field-induced transitions in r2banio5 compounds (r= tm, er, ho, dy, tb, gd, sm, nd, pr)

E García-Matres, JL Garcia-Munoz, JL Martínez… - Journal of magnetism …, 1995 - Elsevier
Magnetic susceptibility and magnetization as a function of temperature and applied field of
the series of nickelates with the general formula R2BaNiO5 have been measured. At …