It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Halogen bonding, the noncovalent interaction based on electrophilic halogen substituents,
features very interesting properties, as illustrated by numerous applications continuously …

N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Aliphatic allylic amines are found in a great variety of complex and biorelevant molecules.
The direct allylic C–H amination of alkenes serves as the most straightforward method …

Halogen bonding is a noncovalent interaction similar to hydrogen bonding, which is based
on electrophilic halogen substituents. Hydrogen‐bonding‐based organocatalysis is a well …

Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Chiral sulfoxides are in extremely high demand in nearly every sector of the chemical
industry concerned with the design and development of new synthetic reagents, drugs, and …

In this work, we developed a metal-free and redox-neutral strategy for the selective S-
alkylation of sulfenamides under basic conditions to yield sulfilimines. The key step involves …

Noncovalent interactions like halogen, chalcogen, and pnictogen bonding are known for a
very long time. During the last decade, these interactions have found different applications in …