Expeditious and practical synthesis of tertiary alcohols from esters enabled by highly polarized organometallic compounds under aerobic conditions in Deep Eutectic …

AF Quivelli, G D'Addato, P Vitale, J García-Álvarez… - Tetrahedron, 2021 - Elsevier
An efficient protocol was developed for the synthesis of tertiary alcohols via nucleophilic
addition of organometallic compounds of s-block elements (Grignard and organolithium …

Reactivity of styrenes in micelles: safe, selective, and sustainable functionalization with azides and carboxylic acids

S Hazra, G Kaur, S Handa - ACS Sustainable Chemistry & …, 2021 - ACS Publications
An amphiphile PS-750-M that mimics dipolar-aprotic organic solvents enables N-bromo
succinimide (NBS)-mediated one-pot oxyfunctionalization of styrenes in water under mild …

Unspecific Peroxygenase Catalyzes Selective Remote‐Site Functionalizations

W Li, DL Davis, KJ Speina, CB Monroe… - …, 2024 - Wiley Online Library
We describe the discovery of an unspecific peroxygenase (UPO) variant that catalyzes the
remote‐site functionalization of halogenated and unsaturated hydrocarbons with high …

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

B Ardiansah, H Tanimoto, T Tomohiro… - Chemical …, 2021 - pubs.rsc.org
Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary
alkyl azides were converted to the corresponding carbonyl or imine compounds without any …

Insights into the ruthenium-catalysed selective reduction of cardanol derivatives via transfer hydrogenation: a density functional theory study

S Ahmad, E Crawford, M Bilal, JG de Vries… - Catalysis Science & …, 2023 - pubs.rsc.org
The detailed mechanism for ruthenium-catalysed selective reduction of cardanol derivatives
by transfer hydrogenation has been fully characterised at the B3PW91-D3/ECP2/PCM …

Generation of N–H Imines from α-Azidocarboxylic Acids through Ru-Catalyzed Decarboxylation

HY Jo, JM Lee, E Pietrasiak, E Lee… - The Journal of …, 2021 - ACS Publications
A new method for the synthesis of N–H imines from α-azidocarboxylic acids was developed,
which proceeds through decarboxylative C–C bond cleavage catalyzed by a commercial …

Reactions of Aldehydes and Ketones and Their Derivatives

MG Moloney - Organic Reaction Mechanisms 2020, 2024 - Wiley Online Library
The gold‐catalyzed cyclization of 2‐alkynylarylaldehyde cyclic acetals leads to indanone
derivatives in good‐to‐excellent yields. It is possible to use photoimmobilized Ni clusters on …

[PDF][PDF] Rhodium-Catalyzed β-Carbon Elimination from Unstrained Alcohols as a Strategy for Reversible Carbon-Carbon Bond Activation

M Lutz - 2023 - research-collection.ethz.ch
Carbon–carbon (CC) bonds represent the backbone of virtually all organic matter, including
biomolecules, soft materials, and pharmaceuticals. At the same time, they are among the …

Decarbonylative Issues Involved in Ru (II)‐Catalyzed [6+ 2− 1] Annulation Reaction of Hydroxychromone with Alkyne: A DFT Study

B Ling, J Wang, Y Liu, YY Jiang, P Liu… - European Journal of …, 2021 - Wiley Online Library
Density functional theory calculations have been performed to explore the Ru‐catalyzed
decarbonylative annulation reaction of 3‐hydroxy‐2‐phenyl‐chromone with an alkyne to …

[图书][B] Copper-Catalyzed Dehydrogenative Decarboxylation Reactions of Carboxylic Acids to Alkenes

MP Stanton - 2023 - search.proquest.com
Linear alpha olefins (LAOs) are important building blocks in the production of linear
lowdensity polyethylene, a plastic used in products such as shrink wraps, plastic bags …