Owing to their three dimensionality and high porosity, metal-organic frameworks (MOFs)
have attracted the attention of scientists especially chemists and material engineers. The …

Fluorinated organic molecules are generally chemically stable and have low electric
polarizability because of the high electronegativity of fluorine. The use of fluorinated organic …

Fluorine, the element with the highest electronegativity and low electric polarizability, can
produce a variety of characteristics, including specific adsorption sites for molecules as well …

Fluorine has been shown to be a promising candidate of H 2 physisorption center. First-
principles calculations reported here provide a fundamental insight into the role of fluorine in …

Ambient conditions sorption isotherms of dihydrogen in a series of various levels of Cu-
exchanged ZSM-5 zeolites, with two different Si/Al ratios, namely 11.5 and 25, show the …

In this paper, we report the synthesis of two new derivatives, bis (3-(3-(trifluoromethyl)-1 H-1,
2, 4-triazol-5-yl)-4, 4′-azo-and-azoxyfurazans by selective oxidation of 4-(3-(trifluoromethyl) …

Fluids confined in nanopores exhibit significant deviations in their structure and dynamics
from the bulk behavior. Although phase, structural, and diffusive behaviors of confined fluids …

To achieve optimal performance in gas storage and delivery applications, metal–organic
frameworks (MOFs) must combine high gravimetric and volumetric capacities. One potential …

Experimental sorption measurements, inelastic neutron scattering (INS), and theoretical
studies of H2 sorption were performed in α-[Mg3 (O2CH) 6], a metal–organic framework …

The inelastic scattering of neutrons from adsorbed H2 is an effective and highly sensitive
method for obtaining molecular level information on the type and nature of H2 binding sites …