Carbon monoxide is an indispensable C1 building block that has been recognized as a
potent feedstock for synthesizing carbonyl-containing molecules. Carbonylative reactions …

1-Methylcyclopropyl aryl ethers (McPAEs) can be viewed as cyclized derivatives of their O-
tert-butyl counterparts. Although these compounds can find use in medicinal chemistry, they …

We disclose herein our detailed investigation into the Barton copper‐promoted C3‐arylation
of indoles using triarylbismuth bis (trifluoroacetates). The arylation of unsubstituted 1H …

The direct S-cyclopropylation of thiophenols using tricyclopropylbismuth is reported. The
reaction is catalyzed by copper (II) acetate and operates under mild conditions to afford the …

Triarylbismuths were found to be highly efficient arylating reagents for copper-promoted N-
arylation of secondary and some heteroaryl and aliphatic primary amines with over 49 …

A simple protocol for the regioselective N‐arylation of the indole side chain of tryptophan
using triarylbismuth reagents as the arylating agent is reported. The reaction is catalyzed by …

A cascade reaction of 3-hydroxy-2-phenylisoindolin-1-one and cyclopropyl ketone has been
developed via a BrØnsted acid-promoted ring-opening/intramolecular cross …

We report herein our detailed investigation on the histidine-directed backbone arylation of
histidine-containing peptides using triarylbismuth reagents. The reaction proceeds on the …

A general method for the O‐arylation of the side chain of tyrosine using triarylbismuth
reagents is reported. The reaction is mediated by copper diacetate, operates at 50° C under …

The copper-promoted S-cyclopropylation of thiophenols using cyclopropylboronic acid is
reported. The procedure operates under simple conditions to afford the corresponding aryl …